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Bibliographic Details
Main Authors: Bluhm, Andreas, Lemm, Marius, Möbus, Tim, Siebert, Oliver
Format: Preprint
Published: 2025
Subjects:
Online Access:https://arxiv.org/abs/2510.08471
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author Bluhm, Andreas
Lemm, Marius
Möbus, Tim
Siebert, Oliver
author_facet Bluhm, Andreas
Lemm, Marius
Möbus, Tim
Siebert, Oliver
contents The first-principles formulation of quantum mechanics relevant for quantum chemistry and trapped quantum gases involves particles in the continuous space $\mathbb R^d$. We present a unified framework and modular algorithm for learning external potentials $V$ with free-fermion models in the continuum. Compared to the lattice-based approaches, the continuum presents new mathematical challenges: the state space is infinite-dimensional and the Hamiltonian contains the Laplacian, which is unbounded in the continuum and produces an unbounded speed of information propagation. We address these through novel optimization methods and information-propagation bounds in combination with a priori regularity assumptions on the external potential. The resulting algorithm provides a unified and robust approach to learn parametric interactions (e.g., Coulomb potentials or periodic potentials) and general smooth functions. Our results lay the foundation for a scalable and generalizable toolkit to learn Hamiltonians in continuous space.
format Preprint
id arxiv_https___arxiv_org_abs_2510_08471
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Learning Coulomb Potentials and Beyond with Free Fermions in Continuous Space
Bluhm, Andreas
Lemm, Marius
Möbus, Tim
Siebert, Oliver
Quantum Physics
Mathematical Physics
The first-principles formulation of quantum mechanics relevant for quantum chemistry and trapped quantum gases involves particles in the continuous space $\mathbb R^d$. We present a unified framework and modular algorithm for learning external potentials $V$ with free-fermion models in the continuum. Compared to the lattice-based approaches, the continuum presents new mathematical challenges: the state space is infinite-dimensional and the Hamiltonian contains the Laplacian, which is unbounded in the continuum and produces an unbounded speed of information propagation. We address these through novel optimization methods and information-propagation bounds in combination with a priori regularity assumptions on the external potential. The resulting algorithm provides a unified and robust approach to learn parametric interactions (e.g., Coulomb potentials or periodic potentials) and general smooth functions. Our results lay the foundation for a scalable and generalizable toolkit to learn Hamiltonians in continuous space.
title Learning Coulomb Potentials and Beyond with Free Fermions in Continuous Space
topic Quantum Physics
Mathematical Physics
url https://arxiv.org/abs/2510.08471