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| Main Author: | |
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| Format: | Recurso digital |
| Language: | English |
| Published: |
Zenodo
2025
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| Subjects: | |
| Online Access: | https://doi.org/10.5281/zenodo.16610847 |
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Table of Contents:
- <table> <tbody> <tr> <td> <div> <div> <p><span lang="EN-IN">This study investigates the electrochemical behavior of selected p, d and f block elements and their complexes using various voltammetric techniques. Cyclic voltammetry (CV), differential pulse voltammetry (DPV), and square wave voltammetry (SWV) were employed to examine the redox properties of gallium, indium, thallium, copper, silver, gold, lanthanum, cerium, and their complexes with organic ligands. The effects of scan rate, pH, supporting electrolyte, and ligand structure on the voltammetric response were systematically evaluated. Diffusion coefficients and heterogeneous electron transfer rate constants were determined. The formation constants of metal complexes were calculated from voltammetric data. This comprehensive electrochemical characterization provides insights into the redox chemistry and coordination behavior of these elements, with implications for analytical, environmental, and materials science applications.</span></p> </div> </div> </td> </tr> </tbody> </table>