Self-assembled porous media from particle-stabilized emulsions

Fuente: arXiv
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Autores principales: Frijters, Stefan, Harting, Jens
Formato: Preprint
Publicado: 2014
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author Frijters, Stefan
Harting, Jens
author_facet Frijters, Stefan
Harting, Jens
contents We propose a new mechanism to create self-assembled porous media with highly tunable geometrical properties and permeabilities: We first allow a particle-stabilized emulsion to form from a mixture of two fluids and colloidal particles. Then, either one fluid phase or the particle layer is solidified, which can be achieved by techniques such as polymerization or freezing. Based on computer simulations we demonstrate that modifying only the particle wettability or concentration results in porous structures with a wide range of pore sizes and a permeability that can be varied by up to three orders of magnitude. We then discuss optimization of these properties for self-assembled filters or reactors and conclude that structures based on so-called "bijels" are most suitable candidates.
format Preprint
id arxiv_https___arxiv_org_abs_1408_2974
institution arXiv
publishDate 2014
record_format arxiv
spellingShingle Self-assembled porous media from particle-stabilized emulsions
Frijters, Stefan
Harting, Jens
Soft Condensed Matter
Materials Science
Chemical Physics
Computational Physics
Fluid Dynamics
We propose a new mechanism to create self-assembled porous media with highly tunable geometrical properties and permeabilities: We first allow a particle-stabilized emulsion to form from a mixture of two fluids and colloidal particles. Then, either one fluid phase or the particle layer is solidified, which can be achieved by techniques such as polymerization or freezing. Based on computer simulations we demonstrate that modifying only the particle wettability or concentration results in porous structures with a wide range of pore sizes and a permeability that can be varied by up to three orders of magnitude. We then discuss optimization of these properties for self-assembled filters or reactors and conclude that structures based on so-called "bijels" are most suitable candidates.
title Self-assembled porous media from particle-stabilized emulsions
topic Soft Condensed Matter
Materials Science
Chemical Physics
Computational Physics
Fluid Dynamics
url https://arxiv.org/abs/1408.2974