Inelastic collisions of ultracold triplet Rb$_\textbf{2}$ molecules in the rovibrational ground state

Fuente: arXiv
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Autores principales: Drews, Björn, Deiß, Markus, Jachymski, Krzysztof, Idziaszek, Zbigniew, Denschlag, Johannes Hecker
Formato: Preprint
Publicado: 2016
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author Drews, Björn
Deiß, Markus
Jachymski, Krzysztof
Idziaszek, Zbigniew
Denschlag, Johannes Hecker
author_facet Drews, Björn
Deiß, Markus
Jachymski, Krzysztof
Idziaszek, Zbigniew
Denschlag, Johannes Hecker
contents Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the vibrational ground state. The measurements are performed with nonpolar $\textrm{Rb}_2$ dimers which are prepared in precisely-defined quantum states and trapped in an array of quasi-1D potential tubes. In particular, we investigate collisions of molecules in the absolute lowest triplet energy level where any inelastic process requires a change of the electronic state. Nevertheless, we find similar decay rates as for collisions between rotationally or vibrationally excited triplet molecules and they are close to the rates for universal reactions. As anticipated theoretically, the measured decay rate constants vary considerably when confinement and collision energy are changed. This might be exploited to control the collisional properties of molecules.
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id arxiv_https___arxiv_org_abs_1606_00722
institution arXiv
publishDate 2016
record_format arxiv
spellingShingle Inelastic collisions of ultracold triplet Rb$_\textbf{2}$ molecules in the rovibrational ground state
Drews, Björn
Deiß, Markus
Jachymski, Krzysztof
Idziaszek, Zbigniew
Denschlag, Johannes Hecker
Quantum Gases
Atomic Physics
Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the vibrational ground state. The measurements are performed with nonpolar $\textrm{Rb}_2$ dimers which are prepared in precisely-defined quantum states and trapped in an array of quasi-1D potential tubes. In particular, we investigate collisions of molecules in the absolute lowest triplet energy level where any inelastic process requires a change of the electronic state. Nevertheless, we find similar decay rates as for collisions between rotationally or vibrationally excited triplet molecules and they are close to the rates for universal reactions. As anticipated theoretically, the measured decay rate constants vary considerably when confinement and collision energy are changed. This might be exploited to control the collisional properties of molecules.
title Inelastic collisions of ultracold triplet Rb$_\textbf{2}$ molecules in the rovibrational ground state
topic Quantum Gases
Atomic Physics
url https://arxiv.org/abs/1606.00722