Gordon decomposition of the magnetizability of a Dirac one-electron atom in an arbitrary discrete energy state

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Auteur principal: Stefańska, Patrycja
Format: Preprint
Publié: 2020
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author Stefańska, Patrycja
author_facet Stefańska, Patrycja
contents We present a Gordon decomposition of the magnetizability of a Dirac one-electron atom in an arbitrary discrete energy eigenstate, with a pointlike, spinless, and motionless nucleus of charge $Ze$. The external magnetic field, by which the atomic state is perturbed, is assumed to be weak, static, and uniform. Using the Sturmian expansion of the generalized Dirac--Coulomb Green function proposed by Szmytkowski in 1997, we derive a closed-form expressions for the diamagnetic ($χ_{d}$) and paramagnetic ($χ_{p}$) contributions to $χ$. Our calculations are purely analytical; the received formula for $χ_{p}$ contains the generalized hypergeometric functions ${}_3F_2$ of the unit argument, while $χ_{d}$ is of an elementary form. For the atomic ground state, both results reduce to the formulas obtained earlier by other author. This work is a prequel to our recent article, where the numerical values of $χ_{d}$ and $χ_{p}$ for some excited states of selected hydrogenlike ions with $1 \leqslant Z \leqslant 137$ were obtained with the use of the general formulas derived here.
format Preprint
id arxiv_https___arxiv_org_abs_2006_03892
institution arXiv
publishDate 2020
record_format arxiv
spellingShingle Gordon decomposition of the magnetizability of a Dirac one-electron atom in an arbitrary discrete energy state
Stefańska, Patrycja
Quantum Physics
We present a Gordon decomposition of the magnetizability of a Dirac one-electron atom in an arbitrary discrete energy eigenstate, with a pointlike, spinless, and motionless nucleus of charge $Ze$. The external magnetic field, by which the atomic state is perturbed, is assumed to be weak, static, and uniform. Using the Sturmian expansion of the generalized Dirac--Coulomb Green function proposed by Szmytkowski in 1997, we derive a closed-form expressions for the diamagnetic ($χ_{d}$) and paramagnetic ($χ_{p}$) contributions to $χ$. Our calculations are purely analytical; the received formula for $χ_{p}$ contains the generalized hypergeometric functions ${}_3F_2$ of the unit argument, while $χ_{d}$ is of an elementary form. For the atomic ground state, both results reduce to the formulas obtained earlier by other author. This work is a prequel to our recent article, where the numerical values of $χ_{d}$ and $χ_{p}$ for some excited states of selected hydrogenlike ions with $1 \leqslant Z \leqslant 137$ were obtained with the use of the general formulas derived here.
title Gordon decomposition of the magnetizability of a Dirac one-electron atom in an arbitrary discrete energy state
topic Quantum Physics
url https://arxiv.org/abs/2006.03892