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Bibliographic Details
Main Authors: Butcher, T. A., Prendeville, L., Rafferty, A., Trtik, P., Boillat, P., Coey, J. M. D.
Format: Preprint
Published: 2021
Subjects:
Online Access:https://arxiv.org/abs/2107.02770
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Table of Contents:
  • The electrosorption of Gd$^{3+}$ ions from aqueous 70 mM Gd(NO$_3$)$_3$ solution in monolithic carbon aerogel electrodes was recorded by dynamic neutron imaging. The aerogels have a bimodal pore size distribution consisting of macropores and mesopores centered at 115 nm and 15 nm, respectively. After the uptake of Gd$^{3+}$ ions by the negatively charged surface of the porous structure, an inhomogeneous magnetic field was applied to the system of discharging electrodes. This led to a convective flow and confinement of Gd(NO$_3$)$_3$ solution in the magnetic field gradient. Thus, a way to desalt and capture paramagnetic ions from an initially homogeneous solution is established.