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Main Authors: Cai, Yongqing, Wang, Yuan, Hao, Zhanyang, Liu, Yixuan, Ma, Xiao-Ming, Shen, Zecheng, Jiang, Zhicheng, Yang, Yichen, Liu, Wanling, Jiang, Qi, Liu, Zhengtai, Ye, Mao, Shen, Dawei, Sun, Zhe, Chen, Jiabin, Wang, Le, Liu, Cai, Lin, Junhao, Wang, Jianfeng, Huang, Bing, Mei, Jia-Wei, Chen, Chaoyu
Format: Preprint
Published: 2021
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Online Access:https://arxiv.org/abs/2109.12778
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author Cai, Yongqing
Wang, Yuan
Hao, Zhanyang
Liu, Yixuan
Ma, Xiao-Ming
Shen, Zecheng
Jiang, Zhicheng
Yang, Yichen
Liu, Wanling
Jiang, Qi
Liu, Zhengtai
Ye, Mao
Shen, Dawei
Sun, Zhe
Chen, Jiabin
Wang, Le
Liu, Cai
Lin, Junhao
Wang, Jianfeng
Huang, Bing
Mei, Jia-Wei
Chen, Chaoyu
author_facet Cai, Yongqing
Wang, Yuan
Hao, Zhanyang
Liu, Yixuan
Ma, Xiao-Ming
Shen, Zecheng
Jiang, Zhicheng
Yang, Yichen
Liu, Wanling
Jiang, Qi
Liu, Zhengtai
Ye, Mao
Shen, Dawei
Sun, Zhe
Chen, Jiabin
Wang, Le
Liu, Cai
Lin, Junhao
Wang, Jianfeng
Huang, Bing
Mei, Jia-Wei
Chen, Chaoyu
contents Quantum confinement is a restriction on the motion of electrons in a material to specific region, resulting in discrete energy levels rather than continuous energy bands. In certain materials quantum confinement could dramatically reshape the electronic structure and properties of the surface with respect to the bulk. Here, in the recently discovered kagome superconductor CsV$_3$Sb$_5$ (A=K, Rb, Cs) family of materials, we unveil the dominant role of quantum confinement in determining their surface electronic structure. Combining angle-resolved photoemission spectroscopy (ARPES) measurement and density-functional theory simulation, we report the observations of two-dimensional quantum well states due to the confinement of bulk electron pocket and Dirac cone to the nearly isolated surface layer. The theoretical calculations on the slab model also suggest that the ARPES observed spectra are almost entirely contributed by the top two layers. Our results not only explain the disagreement of band structures between the recent experiments and calculations, but also suggest an equally important role played by quantum confinement, together with strong correlation and band topology, in shaping the electronic properties of this family of materials.
format Preprint
id arxiv_https___arxiv_org_abs_2109_12778
institution arXiv
publishDate 2021
record_format arxiv
spellingShingle Emergence of Quantum Confinement in Topological Kagome Superconductor CsV$_3$Sb$_5$ family
Cai, Yongqing
Wang, Yuan
Hao, Zhanyang
Liu, Yixuan
Ma, Xiao-Ming
Shen, Zecheng
Jiang, Zhicheng
Yang, Yichen
Liu, Wanling
Jiang, Qi
Liu, Zhengtai
Ye, Mao
Shen, Dawei
Sun, Zhe
Chen, Jiabin
Wang, Le
Liu, Cai
Lin, Junhao
Wang, Jianfeng
Huang, Bing
Mei, Jia-Wei
Chen, Chaoyu
Strongly Correlated Electrons
Quantum confinement is a restriction on the motion of electrons in a material to specific region, resulting in discrete energy levels rather than continuous energy bands. In certain materials quantum confinement could dramatically reshape the electronic structure and properties of the surface with respect to the bulk. Here, in the recently discovered kagome superconductor CsV$_3$Sb$_5$ (A=K, Rb, Cs) family of materials, we unveil the dominant role of quantum confinement in determining their surface electronic structure. Combining angle-resolved photoemission spectroscopy (ARPES) measurement and density-functional theory simulation, we report the observations of two-dimensional quantum well states due to the confinement of bulk electron pocket and Dirac cone to the nearly isolated surface layer. The theoretical calculations on the slab model also suggest that the ARPES observed spectra are almost entirely contributed by the top two layers. Our results not only explain the disagreement of band structures between the recent experiments and calculations, but also suggest an equally important role played by quantum confinement, together with strong correlation and band topology, in shaping the electronic properties of this family of materials.
title Emergence of Quantum Confinement in Topological Kagome Superconductor CsV$_3$Sb$_5$ family
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2109.12778