Modulated phases of nematic liquid crystals induced by tetrahedral order

Fuente: arXiv
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Main Authors: Rosseto, Michely P., Selinger, Jonathan V.
Format: Preprint
Published: 2021
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author Rosseto, Michely P.
Selinger, Jonathan V.
author_facet Rosseto, Michely P.
Selinger, Jonathan V.
contents Recent theoretical research has developed a general framework to understand director deformations and modulated phases in nematic liquid crystals. In this framework, there are four fundamental director deformation modes: twist, bend, splay, and a fourth mode $Δ$ related to saddle-splay. The first three of these modes are known to induce modulated phases. Here, we consider modulated phases induced by the fourth mode. We develop a theory for tetrahedral order in liquid crystals, and show that it couples to the $Δ$ mode of director deformation. Because of geometric frustration, the $Δ$ mode cannot fill space by itself, but rather must be accompanied by twist or splay. Hence, it may induce a spontaneous cholesteric phase, with either handedness, or a splay nematic phase.
format Preprint
id arxiv_https___arxiv_org_abs_2112_15218
institution arXiv
publishDate 2021
record_format arxiv
spellingShingle Modulated phases of nematic liquid crystals induced by tetrahedral order
Rosseto, Michely P.
Selinger, Jonathan V.
Soft Condensed Matter
Recent theoretical research has developed a general framework to understand director deformations and modulated phases in nematic liquid crystals. In this framework, there are four fundamental director deformation modes: twist, bend, splay, and a fourth mode $Δ$ related to saddle-splay. The first three of these modes are known to induce modulated phases. Here, we consider modulated phases induced by the fourth mode. We develop a theory for tetrahedral order in liquid crystals, and show that it couples to the $Δ$ mode of director deformation. Because of geometric frustration, the $Δ$ mode cannot fill space by itself, but rather must be accompanied by twist or splay. Hence, it may induce a spontaneous cholesteric phase, with either handedness, or a splay nematic phase.
title Modulated phases of nematic liquid crystals induced by tetrahedral order
topic Soft Condensed Matter
url https://arxiv.org/abs/2112.15218