Magnetostriction in microwave synthesized La0.5Ba0.5CoO3
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arXiv
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| Format: | Preprint |
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2022
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| _version_ | 1866911912883650560 |
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| author | Manikandan, M. Ghosh, A. Mahendiran, R. |
| author_facet | Manikandan, M. Ghosh, A. Mahendiran, R. |
| contents | A single-phase polycrystalline La0.5Ba0.5CoO3-d sample was synthesized by microwave irradiation within 20 minutes of processing time and its structural, magnetic, electrical, and magnetostrictive properties were investigated. While the temperature dependence of field-cooled magnetization (M) in a field of H = 0.5 kOe indicates the onset of ferromagnetic transition at TC = 177 K, irreversibility between the zero field-cooled and field cooled M(T) persists even at H = 3 kOe. M(H) at 10 K does not saturate at the maximum available field and has a much smaller value (0.87 μB/Co in a field of 50 kOe) than 1.9 μB/Co expected for spin-only contribution from intermediate Co3+ and Co4+ spins. The resistivity shows insulating behavior down to 10 K and only a small magnetoresistance (~ 2% for H = 70 kOe) occurs around TC. All these results suggest a magnetically heterogeneous ground state with weakly interacting ferromagnetic clusters coexisting with a non-ferromagnetic phase. The length of the sample expands in the direction of the applied magnetic field (positive magnetostriction) and does not show saturation even at 50 kOe. The magnetostriction has a maximum value (= 252 ppm) at 10 K and it decreases with increasing temperature. The smaller value of magnetostriction compared to the available data on La0.5Sr0.5CoO3 suggests that non-ferromagnetic matrix is most likely antiferromagnetic and it restrains the field-induced expansion of ferromagnetic clusters in the microwave synthesized La0.5Ba0.5CoO3-d sample. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2201_12979 |
| institution | arXiv |
| publishDate | 2022 |
| record_format | arxiv |
| spellingShingle | Magnetostriction in microwave synthesized La0.5Ba0.5CoO3 Manikandan, M. Ghosh, A. Mahendiran, R. Materials Science A single-phase polycrystalline La0.5Ba0.5CoO3-d sample was synthesized by microwave irradiation within 20 minutes of processing time and its structural, magnetic, electrical, and magnetostrictive properties were investigated. While the temperature dependence of field-cooled magnetization (M) in a field of H = 0.5 kOe indicates the onset of ferromagnetic transition at TC = 177 K, irreversibility between the zero field-cooled and field cooled M(T) persists even at H = 3 kOe. M(H) at 10 K does not saturate at the maximum available field and has a much smaller value (0.87 μB/Co in a field of 50 kOe) than 1.9 μB/Co expected for spin-only contribution from intermediate Co3+ and Co4+ spins. The resistivity shows insulating behavior down to 10 K and only a small magnetoresistance (~ 2% for H = 70 kOe) occurs around TC. All these results suggest a magnetically heterogeneous ground state with weakly interacting ferromagnetic clusters coexisting with a non-ferromagnetic phase. The length of the sample expands in the direction of the applied magnetic field (positive magnetostriction) and does not show saturation even at 50 kOe. The magnetostriction has a maximum value (= 252 ppm) at 10 K and it decreases with increasing temperature. The smaller value of magnetostriction compared to the available data on La0.5Sr0.5CoO3 suggests that non-ferromagnetic matrix is most likely antiferromagnetic and it restrains the field-induced expansion of ferromagnetic clusters in the microwave synthesized La0.5Ba0.5CoO3-d sample. |
| title | Magnetostriction in microwave synthesized La0.5Ba0.5CoO3 |
| topic | Materials Science |
| url | https://arxiv.org/abs/2201.12979 |