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Main Authors: Tan, Zuoquan, Xing, Xianqin, Fang, Yimei, Huang, Le, Wu, Shunqing, Zhang, Zhiyong, Wang, Le, Chen, Xiangping, Chen, Shanshan
Format: Preprint
Published: 2022
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Online Access:https://arxiv.org/abs/2204.00194
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author Tan, Zuoquan
Xing, Xianqin
Fang, Yimei
Huang, Le
Wu, Shunqing
Zhang, Zhiyong
Wang, Le
Chen, Xiangping
Chen, Shanshan
author_facet Tan, Zuoquan
Xing, Xianqin
Fang, Yimei
Huang, Le
Wu, Shunqing
Zhang, Zhiyong
Wang, Le
Chen, Xiangping
Chen, Shanshan
contents The growth of high-quality Bernal-stacked bilayer graphene (BLG) directly on dielectric substrates is crucial for electronic and optoelectronic applications, but there are still challenges such as poor quality, uncontrollable thickness and polycrystalline films. In this work, a novel method to grow high-quality and single-crystalline BLG directly on various dielectric substrates (SiO2/Si, sapphire, and quartz) was demonstrated. Single-crystalline monolayer graphene was applied as a seeding layer to facilitate the homo-epitaxial synthesis of single-crystalline BLG directly on insulating substrates. The Cu nano-powders (Cu NPs) with nanostructure and high surface-area were used as the remote catalysis to provide long-lasting catalytic activity during the graphene growth. The TEM results confirm the single-crystalline nature of the BLG domains, which validates the superiority of the homo-epitaxial growth technique. The as-grown BLG show comparable quality with the CVD-grown BLG on metal surface. Field-effect transistors directly fabricated on the as-grown BLG/SiO2/Si showed a room temperature carrier mobility as high as 2297cm2/Vs.
format Preprint
id arxiv_https___arxiv_org_abs_2204_00194
institution arXiv
publishDate 2022
record_format arxiv
spellingShingle Direct synthesis of single-crystal bilayer graphene on dielectric substrate
Tan, Zuoquan
Xing, Xianqin
Fang, Yimei
Huang, Le
Wu, Shunqing
Zhang, Zhiyong
Wang, Le
Chen, Xiangping
Chen, Shanshan
Materials Science
The growth of high-quality Bernal-stacked bilayer graphene (BLG) directly on dielectric substrates is crucial for electronic and optoelectronic applications, but there are still challenges such as poor quality, uncontrollable thickness and polycrystalline films. In this work, a novel method to grow high-quality and single-crystalline BLG directly on various dielectric substrates (SiO2/Si, sapphire, and quartz) was demonstrated. Single-crystalline monolayer graphene was applied as a seeding layer to facilitate the homo-epitaxial synthesis of single-crystalline BLG directly on insulating substrates. The Cu nano-powders (Cu NPs) with nanostructure and high surface-area were used as the remote catalysis to provide long-lasting catalytic activity during the graphene growth. The TEM results confirm the single-crystalline nature of the BLG domains, which validates the superiority of the homo-epitaxial growth technique. The as-grown BLG show comparable quality with the CVD-grown BLG on metal surface. Field-effect transistors directly fabricated on the as-grown BLG/SiO2/Si showed a room temperature carrier mobility as high as 2297cm2/Vs.
title Direct synthesis of single-crystal bilayer graphene on dielectric substrate
topic Materials Science
url https://arxiv.org/abs/2204.00194