A Graph Neural Network-Based Approach to XANES Data Analysis

Fuente: arXiv
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Main Authors: Zhan, Fei, Zheng, Lirong, Yao, Haodong, Geng, Zhi, Yu, Can, Han, Xue, Song, Xueqi, Chen, Shuguang, Zhao, Haifeng
Format: Preprint
Published: 2022
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author Zhan, Fei
Zheng, Lirong
Yao, Haodong
Geng, Zhi
Yu, Can
Han, Xue
Song, Xueqi
Chen, Shuguang
Zhao, Haifeng
author_facet Zhan, Fei
Zheng, Lirong
Yao, Haodong
Geng, Zhi
Yu, Can
Han, Xue
Song, Xueqi
Chen, Shuguang
Zhao, Haifeng
contents X-ray absorption spectroscopy (XAS) is an indispensable tool to characterize the atomic-scale three-dimensional local structure of the system, in which XANES is the most important energy region to reflect the three-dimensional structure. However quantitative analysis of three-dimensional structure from XANES requires users to have a deep understanding and accurate judgment of structural information and summarize several structural parameters, which is often difficult to achieve. In this work, We construct \textbf{physics-informed Graph neural network} and \textbf{Transformer} models for calculating XANES from the input three-dimensional structure; we improve the efficiency of the model based on the physical meaning of XAS; then we combine the model and optimization algorithm to fit the three-dimensional structure of given system. This method does not require users to summarize the structural parameters, has wide application range. It can be applied to the three-dimensional structure analysis of solid materials and has positive significance for the study of structure-function relationship in the fields of energy and catalysis. In addition, this method is expected to be developed into an online three-dimensional structure analysis method for XAS related beamlines.
format Preprint
id arxiv_https___arxiv_org_abs_2205_04463
institution arXiv
publishDate 2022
record_format arxiv
spellingShingle A Graph Neural Network-Based Approach to XANES Data Analysis
Zhan, Fei
Zheng, Lirong
Yao, Haodong
Geng, Zhi
Yu, Can
Han, Xue
Song, Xueqi
Chen, Shuguang
Zhao, Haifeng
Chemical Physics
X-ray absorption spectroscopy (XAS) is an indispensable tool to characterize the atomic-scale three-dimensional local structure of the system, in which XANES is the most important energy region to reflect the three-dimensional structure. However quantitative analysis of three-dimensional structure from XANES requires users to have a deep understanding and accurate judgment of structural information and summarize several structural parameters, which is often difficult to achieve. In this work, We construct \textbf{physics-informed Graph neural network} and \textbf{Transformer} models for calculating XANES from the input three-dimensional structure; we improve the efficiency of the model based on the physical meaning of XAS; then we combine the model and optimization algorithm to fit the three-dimensional structure of given system. This method does not require users to summarize the structural parameters, has wide application range. It can be applied to the three-dimensional structure analysis of solid materials and has positive significance for the study of structure-function relationship in the fields of energy and catalysis. In addition, this method is expected to be developed into an online three-dimensional structure analysis method for XAS related beamlines.
title A Graph Neural Network-Based Approach to XANES Data Analysis
topic Chemical Physics
url https://arxiv.org/abs/2205.04463