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Main Author: Hastings, Matthew B.
Format: Preprint
Published: 2022
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Online Access:https://arxiv.org/abs/2205.12325
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author Hastings, Matthew B.
author_facet Hastings, Matthew B.
contents The sum-of-squares (SoS) hierarchy is a powerful technique based on semi-definite programming that can be used for both classical and quantum optimization problems. This hierarchy goes under several names; in particular, in quantum chemistry it is called the reduced density matrix (RDM) method. We consider the ability of this hierarchy to reproduce weak coupling perturbation theory for three different kinds of systems: spin (or qubit) systems, bosonic systems (the anharmonic oscillator), and fermionic systems with quartic interactions. For such fermionic systems, we show that degree-$4$ SoS (called $2$-RDM in quantum chemsitry) does not reproduce second order perturbation theory but degree-$6$ SoS ($3$-RDM) does (and we conjecture that it reproduces third order perturbation theory). Indeed, we identify a fragment of degree-$6$ SoS which can do this, which may be useful for practical quantum chemical calculations as it may be possible to implement this fragment with less cost than the full degree-$6$ SoS. Remarkably, this fragment is very similar to one studied by Hastings and O'Donnell for the Sachdev-Ye-Kitaev (SYK) model.
format Preprint
id arxiv_https___arxiv_org_abs_2205_12325
institution arXiv
publishDate 2022
record_format arxiv
spellingShingle Perturbation Theory and the Sum of Squares
Hastings, Matthew B.
Strongly Correlated Electrons
High Energy Physics - Theory
Quantum Physics
The sum-of-squares (SoS) hierarchy is a powerful technique based on semi-definite programming that can be used for both classical and quantum optimization problems. This hierarchy goes under several names; in particular, in quantum chemistry it is called the reduced density matrix (RDM) method. We consider the ability of this hierarchy to reproduce weak coupling perturbation theory for three different kinds of systems: spin (or qubit) systems, bosonic systems (the anharmonic oscillator), and fermionic systems with quartic interactions. For such fermionic systems, we show that degree-$4$ SoS (called $2$-RDM in quantum chemsitry) does not reproduce second order perturbation theory but degree-$6$ SoS ($3$-RDM) does (and we conjecture that it reproduces third order perturbation theory). Indeed, we identify a fragment of degree-$6$ SoS which can do this, which may be useful for practical quantum chemical calculations as it may be possible to implement this fragment with less cost than the full degree-$6$ SoS. Remarkably, this fragment is very similar to one studied by Hastings and O'Donnell for the Sachdev-Ye-Kitaev (SYK) model.
title Perturbation Theory and the Sum of Squares
topic Strongly Correlated Electrons
High Energy Physics - Theory
Quantum Physics
url https://arxiv.org/abs/2205.12325