Random packing fraction of binary similar particles: Onsager's excluded volume model revisited
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arXiv
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| Natura: | Preprint |
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2022
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| _version_ | 1866911934133043200 |
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| author | Brouwers, H. J. H. |
| author_facet | Brouwers, H. J. H. |
| contents | In this paper, the binary random packing fraction of similar particles with size ratios ranging from unity to well over 2 is studied. The classic excluded volume model for spherocylinders and cylinders proposed by Onsager [1] is revisited to derive an asymptotically correct expression for these binary packings. the packing fraction increase by binary polydispersity equals 2f(1 - f)X1(1 - X1)(u - 1)^2 + O((u - 1)^3), where f is the monosized packing fraction, X1 is the number fraction of a component, and u is the size ratio of the two particles. This equation is in excellent agreement with the semi-empirical expression provided by Mangelsdorf and Washington [2] for random close packing (RCP) of spheres. Combining both approaches, a generic explicit equation for the bidisperse packing fraction is proposed. This expression is extensively compared with computer simulations of the random close packing of binary spherocylinder packings, spheres included, and random loose sphere packings (1 < u < 2 and beyond). The derived generic closed-form equation appears to be in excellent agreement with the collection of computer-generated packing data using four different computer algorithms and RCP and random loose packing (RLP) compaction states. Furthermore, the present analysis yields a monodisperse packing fraction map of a wide collection of particle shapes at different compaction states. The explicit boundaries of this map appear to be in good agreement with a broad collection of random close and random loose packing data. Appendix A presents an overview of published monodisperse packing fractions of (sphero)cylinders for aspect ratios from zero to infinity, and at RLP and RCP packing configurations, and they are related to Onsager's theory. Appendix B presents a derivation the binary packing fraction of disks in a plane (R^2) and hyperspheres in R^D (D > 3) with small size difference. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2209_09873 |
| institution | arXiv |
| publishDate | 2022 |
| record_format | arxiv |
| spellingShingle | Random packing fraction of binary similar particles: Onsager's excluded volume model revisited Brouwers, H. J. H. Other Condensed Matter In this paper, the binary random packing fraction of similar particles with size ratios ranging from unity to well over 2 is studied. The classic excluded volume model for spherocylinders and cylinders proposed by Onsager [1] is revisited to derive an asymptotically correct expression for these binary packings. the packing fraction increase by binary polydispersity equals 2f(1 - f)X1(1 - X1)(u - 1)^2 + O((u - 1)^3), where f is the monosized packing fraction, X1 is the number fraction of a component, and u is the size ratio of the two particles. This equation is in excellent agreement with the semi-empirical expression provided by Mangelsdorf and Washington [2] for random close packing (RCP) of spheres. Combining both approaches, a generic explicit equation for the bidisperse packing fraction is proposed. This expression is extensively compared with computer simulations of the random close packing of binary spherocylinder packings, spheres included, and random loose sphere packings (1 < u < 2 and beyond). The derived generic closed-form equation appears to be in excellent agreement with the collection of computer-generated packing data using four different computer algorithms and RCP and random loose packing (RLP) compaction states. Furthermore, the present analysis yields a monodisperse packing fraction map of a wide collection of particle shapes at different compaction states. The explicit boundaries of this map appear to be in good agreement with a broad collection of random close and random loose packing data. Appendix A presents an overview of published monodisperse packing fractions of (sphero)cylinders for aspect ratios from zero to infinity, and at RLP and RCP packing configurations, and they are related to Onsager's theory. Appendix B presents a derivation the binary packing fraction of disks in a plane (R^2) and hyperspheres in R^D (D > 3) with small size difference. |
| title | Random packing fraction of binary similar particles: Onsager's excluded volume model revisited |
| topic | Other Condensed Matter |
| url | https://arxiv.org/abs/2209.09873 |