Raman spectroscopic characterization of crater walls formed upon single-shot high energy femtosecond laser irradiation of dimethacrylate polymer doped with plasmonic gold nanorods

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Hauptverfasser: Rigó, István, Kámán, Judit, Szokol, Ágnes Nagyné, Bonyár, Attila, Szalóki, Melinda, Borók, Alexandra, Zangana, Shereen, Rácz, Péter, Aladi, Márk, Kedves, Miklós Ákos, Galbács, Gábor, Csernai, László P., Biró, Tamás S., Kroó, Norbert, Veres, Miklós, Collaboration, NAPLIFE
Format: Preprint
Veröffentlicht: 2022
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author Rigó, István
Kámán, Judit
Szokol, Ágnes Nagyné
Bonyár, Attila
Szalóki, Melinda
Borók, Alexandra
Zangana, Shereen
Rácz, Péter
Aladi, Márk
Kedves, Miklós Ákos
Galbács, Gábor
Csernai, László P.
Biró, Tamás S.
Kroó, Norbert
Veres, Miklós
Collaboration, NAPLIFE
author_facet Rigó, István
Kámán, Judit
Szokol, Ágnes Nagyné
Bonyár, Attila
Szalóki, Melinda
Borók, Alexandra
Zangana, Shereen
Rácz, Péter
Aladi, Márk
Kedves, Miklós Ákos
Galbács, Gábor
Csernai, László P.
Biró, Tamás S.
Kroó, Norbert
Veres, Miklós
Collaboration, NAPLIFE
contents The bonding configuration of the crater walls formed in urethane dimethacrylate-based polymer doped with plasmonic gold nanorods upon irradiation with a single-shot high-energy femtosecond laser pulse has been studied by Raman spectroscopy. New Raman bands were detected in the 2000-2500 cm-1 region of the Raman spectrum the intensities of which showed strong dependence on the concentration of the plasmonic nanoparticles and the energy of the laser pulse. Based on model calculations of the Raman frequencies of the polymer these peaks were attributed to carbon-deuterium and nitrogen-deuterium vibrations. Their appearance might indicate the occurrence of nuclear reactions in the polymer excited by the ultra-strong laser field amplified by the plasmonic nanoparticles.
format Preprint
id arxiv_https___arxiv_org_abs_2210_00619
institution arXiv
publishDate 2022
record_format arxiv
spellingShingle Raman spectroscopic characterization of crater walls formed upon single-shot high energy femtosecond laser irradiation of dimethacrylate polymer doped with plasmonic gold nanorods
Rigó, István
Kámán, Judit
Szokol, Ágnes Nagyné
Bonyár, Attila
Szalóki, Melinda
Borók, Alexandra
Zangana, Shereen
Rácz, Péter
Aladi, Márk
Kedves, Miklós Ákos
Galbács, Gábor
Csernai, László P.
Biró, Tamás S.
Kroó, Norbert
Veres, Miklós
Collaboration, NAPLIFE
Plasma Physics
Optics
The bonding configuration of the crater walls formed in urethane dimethacrylate-based polymer doped with plasmonic gold nanorods upon irradiation with a single-shot high-energy femtosecond laser pulse has been studied by Raman spectroscopy. New Raman bands were detected in the 2000-2500 cm-1 region of the Raman spectrum the intensities of which showed strong dependence on the concentration of the plasmonic nanoparticles and the energy of the laser pulse. Based on model calculations of the Raman frequencies of the polymer these peaks were attributed to carbon-deuterium and nitrogen-deuterium vibrations. Their appearance might indicate the occurrence of nuclear reactions in the polymer excited by the ultra-strong laser field amplified by the plasmonic nanoparticles.
title Raman spectroscopic characterization of crater walls formed upon single-shot high energy femtosecond laser irradiation of dimethacrylate polymer doped with plasmonic gold nanorods
topic Plasma Physics
Optics
url https://arxiv.org/abs/2210.00619