Electronic Janus lattice and kagome-like bands in coloring-triangular MoTe2 monolayers

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Hauptverfasser: Lei, Le, Dai, Jiaqi, Dong, Haoyu, Geng, Yanyan, Cao, Feiyue, Wang, Cong, Xu, Rui, Pang, Fei, Li, Fangsen, Cheng, Zhihai, Wang, Guang, Ji, Wei
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Veröffentlicht: 2023
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author Lei, Le
Dai, Jiaqi
Dong, Haoyu
Geng, Yanyan
Cao, Feiyue
Wang, Cong
Xu, Rui
Pang, Fei
Li, Fangsen
Cheng, Zhihai
Wang, Guang
Ji, Wei
author_facet Lei, Le
Dai, Jiaqi
Dong, Haoyu
Geng, Yanyan
Cao, Feiyue
Wang, Cong
Xu, Rui
Pang, Fei
Li, Fangsen
Cheng, Zhihai
Wang, Guang
Ji, Wei
contents Polymorphic structures of transition-metal dichalcogenides (TMDs) host exotic electronic states, like charge density wave and superconductivity. However, the number of these structures is limited by crystal symmetries, which poses a challenge to achieve tailored lattices and properties both theoretically and experimentally. Here, we report a coloring-triangle (CT) latticed MoTe2 monolayer, termed CT-MoTe2, constructed by controllably introducing uniform and ordered mirror-twin-boundaries into a pristine monolayer in molecular beam epitaxy. Low-temperature scanning tunneling microscopy and spectroscopy (STM/STS) together with theoretical calculations reveal that the monolayer has an electronic Janus lattice, i.e., an energy-dependent atomic-lattice and a pseudo-Te sublattice, and shares the identical geometry with the Mo5Te8 layer. Dirac-like and flat electronic bands inherently existing in the CT lattice are identified by two broad and two prominent peaks in STS spectra, respectively, and verified with density-functional-theory calculations. Two types of intrinsic domain boundaries were observed, in one of which the electronic-Janus-lattice feature maintains, implying potential applications as an energy-tunable electron-tunneling barrier in future functional devices.
format Preprint
id arxiv_https___arxiv_org_abs_2302_06166
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Electronic Janus lattice and kagome-like bands in coloring-triangular MoTe2 monolayers
Lei, Le
Dai, Jiaqi
Dong, Haoyu
Geng, Yanyan
Cao, Feiyue
Wang, Cong
Xu, Rui
Pang, Fei
Li, Fangsen
Cheng, Zhihai
Wang, Guang
Ji, Wei
Materials Science
Polymorphic structures of transition-metal dichalcogenides (TMDs) host exotic electronic states, like charge density wave and superconductivity. However, the number of these structures is limited by crystal symmetries, which poses a challenge to achieve tailored lattices and properties both theoretically and experimentally. Here, we report a coloring-triangle (CT) latticed MoTe2 monolayer, termed CT-MoTe2, constructed by controllably introducing uniform and ordered mirror-twin-boundaries into a pristine monolayer in molecular beam epitaxy. Low-temperature scanning tunneling microscopy and spectroscopy (STM/STS) together with theoretical calculations reveal that the monolayer has an electronic Janus lattice, i.e., an energy-dependent atomic-lattice and a pseudo-Te sublattice, and shares the identical geometry with the Mo5Te8 layer. Dirac-like and flat electronic bands inherently existing in the CT lattice are identified by two broad and two prominent peaks in STS spectra, respectively, and verified with density-functional-theory calculations. Two types of intrinsic domain boundaries were observed, in one of which the electronic-Janus-lattice feature maintains, implying potential applications as an energy-tunable electron-tunneling barrier in future functional devices.
title Electronic Janus lattice and kagome-like bands in coloring-triangular MoTe2 monolayers
topic Materials Science
url https://arxiv.org/abs/2302.06166