Excitonic effects in energy loss spectra of freestanding graphene
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arXiv
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| Format: | Preprint |
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2023
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| _version_ | 1866915332000579584 |
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| author | Guandalini, Alberto Senga, Ryosuke Lin, Yung-Chang Suenaga, Kazu Ferretti, Andrea Varsano, Daniele Recchia, Andrea Barone, Paolo Mauri, Francesco Pichler, Thomas Kramberger, Christian |
| author_facet | Guandalini, Alberto Senga, Ryosuke Lin, Yung-Chang Suenaga, Kazu Ferretti, Andrea Varsano, Daniele Recchia, Andrea Barone, Paolo Mauri, Francesco Pichler, Thomas Kramberger, Christian |
| contents | In this work we perform electron energy-loss spectroscopy (EELS) of freestanding graphene with high energy and momentum resolution to disentangle the quasielastic scattering from the excitation gap of Dirac electrons close to the optical limit. We show the importance of many-body effects on electronic excitations at finite transferred momentum by comparing measured EELS with ab initio calculations at increasing levels of theory. Quasi-particle corrections and excitonic effects are addressed within the GW approximation and Bethe-Salpeter equation, respectively. Both effects are essential in the description of the EEL spectra to obtain a quantitative agreement with experiments, with the position, dispersion, and shape of both the excitation gap and the $π$ plasmon being significantly affected by excitonic effects. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2302_06367 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Excitonic effects in energy loss spectra of freestanding graphene Guandalini, Alberto Senga, Ryosuke Lin, Yung-Chang Suenaga, Kazu Ferretti, Andrea Varsano, Daniele Recchia, Andrea Barone, Paolo Mauri, Francesco Pichler, Thomas Kramberger, Christian Materials Science In this work we perform electron energy-loss spectroscopy (EELS) of freestanding graphene with high energy and momentum resolution to disentangle the quasielastic scattering from the excitation gap of Dirac electrons close to the optical limit. We show the importance of many-body effects on electronic excitations at finite transferred momentum by comparing measured EELS with ab initio calculations at increasing levels of theory. Quasi-particle corrections and excitonic effects are addressed within the GW approximation and Bethe-Salpeter equation, respectively. Both effects are essential in the description of the EEL spectra to obtain a quantitative agreement with experiments, with the position, dispersion, and shape of both the excitation gap and the $π$ plasmon being significantly affected by excitonic effects. |
| title | Excitonic effects in energy loss spectra of freestanding graphene |
| topic | Materials Science |
| url | https://arxiv.org/abs/2302.06367 |