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| Main Authors: | , , , , , , , , , , , , , , , |
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| Format: | Preprint |
| Published: |
2023
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2303.06072 |
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| _version_ | 1866913187960455168 |
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| author | Singh, Maninderjeet Das, Priyanka Samanta, Pabitra Narayan Bera, Sumit Tanthirige, Ruskshan Shook, Brian Nejat, Roshanak Behera, Banarji Zhang, Qiqi Dai, Qilin Pramanik, Avijit Ray, Paresh Raghavan, Dharmaraj Leszczysnki, Jerzy Karim, Alamgir Pradhan, Nihar R. |
| author_facet | Singh, Maninderjeet Das, Priyanka Samanta, Pabitra Narayan Bera, Sumit Tanthirige, Ruskshan Shook, Brian Nejat, Roshanak Behera, Banarji Zhang, Qiqi Dai, Qilin Pramanik, Avijit Ray, Paresh Raghavan, Dharmaraj Leszczysnki, Jerzy Karim, Alamgir Pradhan, Nihar R. |
| contents | Dielectric capacitors are critical components in electronics and energy storage devices. The polymer based dielectric capacitors have advantages of flexibility, fast charge and discharge, low loss, and graceful failure. Elevating the use of polymeric dielectric capacitors for advanced energy applications such as electric vehicles (EVs) however requires significant enhancement of their energy densities. Here, we report a polymer thin film heterostructure based capacitor of poly(vinylidene fluoride)/poly(methyl methacrylate) with stratified 2D nanofillers (Mica or h-BN nanosheets) (PVDF/PMMA-2D fillers/PVDF), that shows enhanced permittivity, high dielectric strength and an ultra-high energy density of 75 J/cm3 with efficiency over 79%. Density functional theory calculations verify the observed permittivity enhancement. This approach of using oriented 2D nanofillers based polymer heterostructure composites is expected to be universal for designing high energy density thin film polymeric dielectric capacitors for myriads of applications. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2303_06072 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | High Energy Density in layered 2D Nanomaterial based Polymer Dielectric Films Singh, Maninderjeet Das, Priyanka Samanta, Pabitra Narayan Bera, Sumit Tanthirige, Ruskshan Shook, Brian Nejat, Roshanak Behera, Banarji Zhang, Qiqi Dai, Qilin Pramanik, Avijit Ray, Paresh Raghavan, Dharmaraj Leszczysnki, Jerzy Karim, Alamgir Pradhan, Nihar R. Applied Physics Materials Science Dielectric capacitors are critical components in electronics and energy storage devices. The polymer based dielectric capacitors have advantages of flexibility, fast charge and discharge, low loss, and graceful failure. Elevating the use of polymeric dielectric capacitors for advanced energy applications such as electric vehicles (EVs) however requires significant enhancement of their energy densities. Here, we report a polymer thin film heterostructure based capacitor of poly(vinylidene fluoride)/poly(methyl methacrylate) with stratified 2D nanofillers (Mica or h-BN nanosheets) (PVDF/PMMA-2D fillers/PVDF), that shows enhanced permittivity, high dielectric strength and an ultra-high energy density of 75 J/cm3 with efficiency over 79%. Density functional theory calculations verify the observed permittivity enhancement. This approach of using oriented 2D nanofillers based polymer heterostructure composites is expected to be universal for designing high energy density thin film polymeric dielectric capacitors for myriads of applications. |
| title | High Energy Density in layered 2D Nanomaterial based Polymer Dielectric Films |
| topic | Applied Physics Materials Science |
| url | https://arxiv.org/abs/2303.06072 |