Chiral nanoparticle chains on inorganic nanotube templates

Fuente: arXiv
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Autori principali: Kachtík, Lukáš, Citterberg, Daniel, Bukvišová, Kristýna, Kejík, Lukáš, Ligmajer, Filip, Kovařík, Martin, Musálek, Tomáš, Krishnappa, Manjunath, Šikola, Tomáš, Kolíbal, Miroslav
Natura: Preprint
Pubblicazione: 2023
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author Kachtík, Lukáš
Citterberg, Daniel
Bukvišová, Kristýna
Kejík, Lukáš
Ligmajer, Filip
Kovařík, Martin
Musálek, Tomáš
Krishnappa, Manjunath
Šikola, Tomáš
Kolíbal, Miroslav
author_facet Kachtík, Lukáš
Citterberg, Daniel
Bukvišová, Kristýna
Kejík, Lukáš
Ligmajer, Filip
Kovařík, Martin
Musálek, Tomáš
Krishnappa, Manjunath
Šikola, Tomáš
Kolíbal, Miroslav
contents Fabrication of chiral assemblies of plasmonic nanoparticles is a highly attractive and challenging task with promising applications in light emission, detection, and sensing. So far, primarily organic chiral templates have been used for chirality inscription. However, this significantly limits the variety of nanoparticle preparation techniques to an in-pot approach at very low synthesis temperatures. Here, we demonstrate utilization of seemingly achiral inorganic nanotubes as templates for the chiral assembly of nanoparticles. We show that both metallic and dielectric nanoparticles can be attached to scroll-like chiral edges propagating on the surfaces of WS2 nanotubes. Due to relatively high temperature stability of these nanotubes, such assembly can be performed at temperatures as high as 550 °C. This large temperature range significantly widens the portfolio of usable nanoparticle fabrication techniques, allowing us to demonstrate a variety of chiral nanoparticle assemblies, ranging from metals (Au, Ga) and semiconductors (Ge) to oxides (WO3).
format Preprint
id arxiv_https___arxiv_org_abs_2303_16460
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Chiral nanoparticle chains on inorganic nanotube templates
Kachtík, Lukáš
Citterberg, Daniel
Bukvišová, Kristýna
Kejík, Lukáš
Ligmajer, Filip
Kovařík, Martin
Musálek, Tomáš
Krishnappa, Manjunath
Šikola, Tomáš
Kolíbal, Miroslav
Materials Science
Mesoscale and Nanoscale Physics
Applied Physics
Fabrication of chiral assemblies of plasmonic nanoparticles is a highly attractive and challenging task with promising applications in light emission, detection, and sensing. So far, primarily organic chiral templates have been used for chirality inscription. However, this significantly limits the variety of nanoparticle preparation techniques to an in-pot approach at very low synthesis temperatures. Here, we demonstrate utilization of seemingly achiral inorganic nanotubes as templates for the chiral assembly of nanoparticles. We show that both metallic and dielectric nanoparticles can be attached to scroll-like chiral edges propagating on the surfaces of WS2 nanotubes. Due to relatively high temperature stability of these nanotubes, such assembly can be performed at temperatures as high as 550 °C. This large temperature range significantly widens the portfolio of usable nanoparticle fabrication techniques, allowing us to demonstrate a variety of chiral nanoparticle assemblies, ranging from metals (Au, Ga) and semiconductors (Ge) to oxides (WO3).
title Chiral nanoparticle chains on inorganic nanotube templates
topic Materials Science
Mesoscale and Nanoscale Physics
Applied Physics
url https://arxiv.org/abs/2303.16460