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Bibliographic Details
Main Authors: Watanabe, Kana, Nakamura, Tomoki, Morita, Tomoyo
Format: Preprint
Published: 2023
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Online Access:https://arxiv.org/abs/2305.05787
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Table of Contents:
  • Reproduction experiments of radial pyroxene (RP) chondrules were carried out using an Ar-$\mathrm{H_2}$ or Ar gas-jet levitation system in a reducing atmosphere in order to simulate chondrule formation in the protoplanetary disk. The experiments reproduced RP-chondrule textures, consisting of sets of thin pyroxene crystals and mesostasis glass between crystals. However, iron partition coefficients between pyroxene and glassy mesostasis ($\rm{D_{Fe}}$ = Fe mol$\rm{\%_{pyroxene}}$ / Fe mol$\rm{\%_{mesostasis}}$) in natural RP chondrules were much higher than that in experimentally reproduced RP chondrules. The high $\rm{D_{Fe}}$ in natural RP chondrules suggest that iron was removed from the mesostasis melt at high temperatures after the growth of pyroxene crystals. We found that many small iron-metal inclusions had formed in the mesostasis glass, indicating that FeO in the high-temperature melt of mesostasis was reduced to metallic iron, and iron in the mesostasis diffused into the newly formed metal inclusions. The formation of the iron-metal inclusions in the mesostasis was reproduced by our experiments in a reducing atmosphere, confirming that $\rm{D_{Fe}}$ in natural RP chondrules increased after the growth of RP crystals. Therefore, the $\rm{D_{Fe}}$ of RP chondrules can be an indicator to constrain cooling rates and redox states during chondrule formation.