Micellization in active matter of asymmetric self-propelled particles: Experiments

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Main Authors: Molodtsova, Anastasia A., Buzakov, Mikhail K., Burmistrov, Oleg I., Rozenblit, Alina D., Smirnov, Vyacheslav A., Sennikova, Daria V., Porvatov, Vadim A., Puhtina, Ekaterina M., Dmitriev, Alexey A., Olekhno, Nikita A.
Format: Preprint
Published: 2023
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author Molodtsova, Anastasia A.
Buzakov, Mikhail K.
Burmistrov, Oleg I.
Rozenblit, Alina D.
Smirnov, Vyacheslav A.
Sennikova, Daria V.
Porvatov, Vadim A.
Puhtina, Ekaterina M.
Dmitriev, Alexey A.
Olekhno, Nikita A.
author_facet Molodtsova, Anastasia A.
Buzakov, Mikhail K.
Burmistrov, Oleg I.
Rozenblit, Alina D.
Smirnov, Vyacheslav A.
Sennikova, Daria V.
Porvatov, Vadim A.
Puhtina, Ekaterina M.
Dmitriev, Alexey A.
Olekhno, Nikita A.
contents Active matter composed of self-propelled particles features fascinating self-organization phenomena, spanning from motility-induced phase separation to phototaxis to topological excitations depending on the nature and parameters of the system. In the present paper, we consider micelle formation by active particles with a broken symmetry having a circular back and a sharpened nose toward which the particles accelerate. As we demonstrate in experiments with robotic swarms, such particles can either remain in the isotropic phase or form micelles depending on the location of their center of inertia, in accordance with a recent theoretical proposal [T. Kruglov and A. Borisov, Presentations and Videos to 7th Edition of the International Conference on Particle-based Methods (2021), Vol. CT07, p. 2]. Such a behavior is observed for both nonchiral particles moving linearly and placed in a parabolic potential and for chiral particles moving along circular trajectories on a flat surface. By performing experiments with single robots and two-robot collisions, we unveil that the observed emergence of micellization associated with shifting robots' center of inertia towards their noses is governed by at least two-particle effects, in particular, by a difference in the formation of stable two-robot clusters. Finally, we consider the dependence of micelle lifetime and formation probability as well as two-robot collisions on friction between the lateral surfaces of the robots. Crucially, the predicted micellization does not involve any solvation shells that give rise to the micellization of surfactants but is instead driven by an interplay of activity and particle shape asymmetry.
format Preprint
id arxiv_https___arxiv_org_abs_2305_16659
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Micellization in active matter of asymmetric self-propelled particles: Experiments
Molodtsova, Anastasia A.
Buzakov, Mikhail K.
Burmistrov, Oleg I.
Rozenblit, Alina D.
Smirnov, Vyacheslav A.
Sennikova, Daria V.
Porvatov, Vadim A.
Puhtina, Ekaterina M.
Dmitriev, Alexey A.
Olekhno, Nikita A.
Soft Condensed Matter
Statistical Mechanics
Adaptation and Self-Organizing Systems
Active matter composed of self-propelled particles features fascinating self-organization phenomena, spanning from motility-induced phase separation to phototaxis to topological excitations depending on the nature and parameters of the system. In the present paper, we consider micelle formation by active particles with a broken symmetry having a circular back and a sharpened nose toward which the particles accelerate. As we demonstrate in experiments with robotic swarms, such particles can either remain in the isotropic phase or form micelles depending on the location of their center of inertia, in accordance with a recent theoretical proposal [T. Kruglov and A. Borisov, Presentations and Videos to 7th Edition of the International Conference on Particle-based Methods (2021), Vol. CT07, p. 2]. Such a behavior is observed for both nonchiral particles moving linearly and placed in a parabolic potential and for chiral particles moving along circular trajectories on a flat surface. By performing experiments with single robots and two-robot collisions, we unveil that the observed emergence of micellization associated with shifting robots' center of inertia towards their noses is governed by at least two-particle effects, in particular, by a difference in the formation of stable two-robot clusters. Finally, we consider the dependence of micelle lifetime and formation probability as well as two-robot collisions on friction between the lateral surfaces of the robots. Crucially, the predicted micellization does not involve any solvation shells that give rise to the micellization of surfactants but is instead driven by an interplay of activity and particle shape asymmetry.
title Micellization in active matter of asymmetric self-propelled particles: Experiments
topic Soft Condensed Matter
Statistical Mechanics
Adaptation and Self-Organizing Systems
url https://arxiv.org/abs/2305.16659