Refining the weighted subspace-search variational quantum eigensolver: compression of ansätze into a single pure state and optimization of weights
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| Format: | Preprint |
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2023
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| author | Hong, Cheng-Lin Colmenarez, Luis Ding, Lexin Benavides-Riveros, Carlos L. Schilling, Christian |
| author_facet | Hong, Cheng-Lin Colmenarez, Luis Ding, Lexin Benavides-Riveros, Carlos L. Schilling, Christian |
| contents | The weighted subspace-search variational quantum eigensolver (SSVQE) is a prominent algorithm for calculating excited-state properties of molecular quantum systems. In this work, we elaborate on some of its fundamental features with the aim of improving its practical realization. First, we demonstrate that the initial ansätze for various excited states could be prepared into a single pure state through a minimal number of ancilla qubits, followed by the optimization of a subsequent global unitary rotation in the targeted subspace. Since the ancillas' sole purpose is to purify an underlying ensemble $ρ_{\boldsymbol{w}}$ state with spectral weights $\boldsymbol{w}$, their measurement would just collapse $ρ_{\boldsymbol{w}}$ with probabilities $w_j$ to one of its eigenstates $|Ψ_j \rangle$. We thus observe that our realization of SSVQE is equivalent to the original SSVQE improved by importance sampling. Then, we elaborate by numerical means on the potential influence of the auxiliary weights $\boldsymbol{w}$ on the accuracy of the sought-after eigenstates and eigenenergies. Clear trends are discovered which are contrasted with some recent mathematical results concerning the ensemble variational principle that underlies SSVQE. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2306_11844 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Refining the weighted subspace-search variational quantum eigensolver: compression of ansätze into a single pure state and optimization of weights Hong, Cheng-Lin Colmenarez, Luis Ding, Lexin Benavides-Riveros, Carlos L. Schilling, Christian Quantum Physics Strongly Correlated Electrons Chemical Physics The weighted subspace-search variational quantum eigensolver (SSVQE) is a prominent algorithm for calculating excited-state properties of molecular quantum systems. In this work, we elaborate on some of its fundamental features with the aim of improving its practical realization. First, we demonstrate that the initial ansätze for various excited states could be prepared into a single pure state through a minimal number of ancilla qubits, followed by the optimization of a subsequent global unitary rotation in the targeted subspace. Since the ancillas' sole purpose is to purify an underlying ensemble $ρ_{\boldsymbol{w}}$ state with spectral weights $\boldsymbol{w}$, their measurement would just collapse $ρ_{\boldsymbol{w}}$ with probabilities $w_j$ to one of its eigenstates $|Ψ_j \rangle$. We thus observe that our realization of SSVQE is equivalent to the original SSVQE improved by importance sampling. Then, we elaborate by numerical means on the potential influence of the auxiliary weights $\boldsymbol{w}$ on the accuracy of the sought-after eigenstates and eigenenergies. Clear trends are discovered which are contrasted with some recent mathematical results concerning the ensemble variational principle that underlies SSVQE. |
| title | Refining the weighted subspace-search variational quantum eigensolver: compression of ansätze into a single pure state and optimization of weights |
| topic | Quantum Physics Strongly Correlated Electrons Chemical Physics |
| url | https://arxiv.org/abs/2306.11844 |