Discovery of a long-ranged charge order with 1/4 Ge1-dimerization in an antiferromagnetic Kagome metal

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Main Authors: Chen, Ziyuan, Wu, Xueliang, Zhou, Shiming, Zhang, Jiakang, Yin, Ruotong, Li, Yuanji, Li, Mingzhe, Gong, Jiashuo, He, Mingquan, Chai, Yisheng, Zhou, Xiaoyuan, Wang, Yilin, Wang, Aifeng, Yan, Ya-Jun, Feng, Dong-Lai
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Published: 2023
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author Chen, Ziyuan
Wu, Xueliang
Zhou, Shiming
Zhang, Jiakang
Yin, Ruotong
Li, Yuanji
Li, Mingzhe
Gong, Jiashuo
He, Mingquan
Chai, Yisheng
Zhou, Xiaoyuan
Wang, Yilin
Wang, Aifeng
Yan, Ya-Jun
Feng, Dong-Lai
author_facet Chen, Ziyuan
Wu, Xueliang
Zhou, Shiming
Zhang, Jiakang
Yin, Ruotong
Li, Yuanji
Li, Mingzhe
Gong, Jiashuo
He, Mingquan
Chai, Yisheng
Zhou, Xiaoyuan
Wang, Yilin
Wang, Aifeng
Yan, Ya-Jun
Feng, Dong-Lai
contents Exotic quantum states arise from the interplay of various degrees of freedom such as charge, spin, orbital, and lattice. Recently, a novel short-ranged charge order (CO) was discovered deep inside the antiferromagnetic phase of Kagome magnet FeGe, exhibiting close relationships with magnetism. Despite extensive investigations, the CO mechanism remains controversial, mainly because the short-ranged behavior hinders precise identification of CO superstructure. Here, combining multiple experimental techniques, we report the observation of a long-ranged CO in high-quality FeGe samples, which is accompanied with a first-order structural transition. With these high-quality samples, the distorted 2 * 2 * 2 CO superstructure is characterized by a strong dimerization along the c-axis of 1/4 of Ge1-sites in Fe3Ge layers, and in response to that, the 2 * 2 in-plane charge modulations are induced. Moreover, we show that the previously reported short-ranged CO might be related to large occupational disorders at Ge1-site, which upsets the equilibrium of the CO state and the ideal 1 * 1 * 1 structure with very close energies, inducing nanoscale coexistence of these two phases.Our study provides crucial clues for further understanding the CO properties in FeGe and helps to identify the CO mechanism.
format Preprint
id arxiv_https___arxiv_org_abs_2307_07990
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Discovery of a long-ranged charge order with 1/4 Ge1-dimerization in an antiferromagnetic Kagome metal
Chen, Ziyuan
Wu, Xueliang
Zhou, Shiming
Zhang, Jiakang
Yin, Ruotong
Li, Yuanji
Li, Mingzhe
Gong, Jiashuo
He, Mingquan
Chai, Yisheng
Zhou, Xiaoyuan
Wang, Yilin
Wang, Aifeng
Yan, Ya-Jun
Feng, Dong-Lai
Strongly Correlated Electrons
Materials Science
Exotic quantum states arise from the interplay of various degrees of freedom such as charge, spin, orbital, and lattice. Recently, a novel short-ranged charge order (CO) was discovered deep inside the antiferromagnetic phase of Kagome magnet FeGe, exhibiting close relationships with magnetism. Despite extensive investigations, the CO mechanism remains controversial, mainly because the short-ranged behavior hinders precise identification of CO superstructure. Here, combining multiple experimental techniques, we report the observation of a long-ranged CO in high-quality FeGe samples, which is accompanied with a first-order structural transition. With these high-quality samples, the distorted 2 * 2 * 2 CO superstructure is characterized by a strong dimerization along the c-axis of 1/4 of Ge1-sites in Fe3Ge layers, and in response to that, the 2 * 2 in-plane charge modulations are induced. Moreover, we show that the previously reported short-ranged CO might be related to large occupational disorders at Ge1-site, which upsets the equilibrium of the CO state and the ideal 1 * 1 * 1 structure with very close energies, inducing nanoscale coexistence of these two phases.Our study provides crucial clues for further understanding the CO properties in FeGe and helps to identify the CO mechanism.
title Discovery of a long-ranged charge order with 1/4 Ge1-dimerization in an antiferromagnetic Kagome metal
topic Strongly Correlated Electrons
Materials Science
url https://arxiv.org/abs/2307.07990