Effect of Doping on the phase stability and Superconductivity in LaH10

Fuente: arXiv
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Autores principales: Wu, Zepeng, Sun, Yang, Durajski, Artur P., Zheng, Feng, Antropov, Vladimir, Ho, Kai-Ming, Wu, Shunqing
Formato: Preprint
Publicado: 2023
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author Wu, Zepeng
Sun, Yang
Durajski, Artur P.
Zheng, Feng
Antropov, Vladimir
Ho, Kai-Ming
Wu, Shunqing
author_facet Wu, Zepeng
Sun, Yang
Durajski, Artur P.
Zheng, Feng
Antropov, Vladimir
Ho, Kai-Ming
Wu, Shunqing
contents We present a computational investigation into the effects of chemical doping with 15 different elements on phase stability and superconductivity in the LaH10 structure. Most doping elements were found to induce softening of phonon modes, enhancing electron-phonon coupling and improving critical superconducting temperature while weakening dynamical stability. Unlike these dopants, Ce was found to extend the range of dynamical stability for LaH10 by eliminating the van Hove singularity near the Fermi level. The doped compound, La0.75Ce0.25H10, maintains high-temperature superconductivity. We also demonstrate that different Ce doping configurations in the LaH10 structure have a minimal effect on energetic stability and electron-phonon coupling strength. Our findings suggest that Ce is a promising dopant to stabilize LaH10 at lower pressures while preserving its high-temperature superconductivity.
format Preprint
id arxiv_https___arxiv_org_abs_2307_11354
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Effect of Doping on the phase stability and Superconductivity in LaH10
Wu, Zepeng
Sun, Yang
Durajski, Artur P.
Zheng, Feng
Antropov, Vladimir
Ho, Kai-Ming
Wu, Shunqing
Superconductivity
Materials Science
We present a computational investigation into the effects of chemical doping with 15 different elements on phase stability and superconductivity in the LaH10 structure. Most doping elements were found to induce softening of phonon modes, enhancing electron-phonon coupling and improving critical superconducting temperature while weakening dynamical stability. Unlike these dopants, Ce was found to extend the range of dynamical stability for LaH10 by eliminating the van Hove singularity near the Fermi level. The doped compound, La0.75Ce0.25H10, maintains high-temperature superconductivity. We also demonstrate that different Ce doping configurations in the LaH10 structure have a minimal effect on energetic stability and electron-phonon coupling strength. Our findings suggest that Ce is a promising dopant to stabilize LaH10 at lower pressures while preserving its high-temperature superconductivity.
title Effect of Doping on the phase stability and Superconductivity in LaH10
topic Superconductivity
Materials Science
url https://arxiv.org/abs/2307.11354