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Main Authors: Guo, Jianning, Semenok, Dmitrii, Shutov, Grigoriy, Zhou, Di, Chen, Su, Wang, Yulong, Helm, Toni, Luther, Sven, Huang, Xiaoli, Cui, Tian
Format: Preprint
Published: 2023
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Online Access:https://arxiv.org/abs/2307.13067
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author Guo, Jianning
Semenok, Dmitrii
Shutov, Grigoriy
Zhou, Di
Chen, Su
Wang, Yulong
Helm, Toni
Luther, Sven
Huang, Xiaoli
Cui, Tian
author_facet Guo, Jianning
Semenok, Dmitrii
Shutov, Grigoriy
Zhou, Di
Chen, Su
Wang, Yulong
Helm, Toni
Luther, Sven
Huang, Xiaoli
Cui, Tian
contents High pressure plays a crucial role in the field of superconductivity. Compressed hydride superconductors are leaders in the race for a material that can conduct electricity without resistance at high or even room temperature. In the present work, we have discovered new lanthanum superhydride, cubic A15-type La$_4$H$_{23}$, with lower stabilization pressure compared to the reported $\textit{fcc}$ LaH$_{10}$. Superconducting La$_4$H$_{23}$ was obtained by laser heating of LaH$_3$ with ammonia borane at about 120 GPa. Transport measurements reveal the maximum critical temperature $\textit{T}$$_{C}$(onset) = 105 K and the critical field $\textit{H}$$_{C2}$(0) = 32 T at 118 GPa, as evidenced by the sharp drop of electrical resistance and the displacement of superconducting transitions in applied magnetic fields. Moreover, we provide evidence for unconventional transport associated with a pseudogap phase in La$_4$H$_{23}$ using pulsed magnetic fields up to 68 T. A large negative magnetoresistance in the non-superconducting state below 40 K, quasi $\textit{T}$-linear electrical resistance, and a sign-change of its temperature dependence mark the emergence of pseudogap in this hydride. Discovered lanthanum hydride is a new member of the A15 family of superconductors with $\textit{T}$$_C$ exceeding the boiling point of liquid nitrogen.
format Preprint
id arxiv_https___arxiv_org_abs_2307_13067
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Large negative magnetoresistance and pseudogap phase in superconducting A15-type La$_4$H$_{23}$
Guo, Jianning
Semenok, Dmitrii
Shutov, Grigoriy
Zhou, Di
Chen, Su
Wang, Yulong
Helm, Toni
Luther, Sven
Huang, Xiaoli
Cui, Tian
Superconductivity
Materials Science
High pressure plays a crucial role in the field of superconductivity. Compressed hydride superconductors are leaders in the race for a material that can conduct electricity without resistance at high or even room temperature. In the present work, we have discovered new lanthanum superhydride, cubic A15-type La$_4$H$_{23}$, with lower stabilization pressure compared to the reported $\textit{fcc}$ LaH$_{10}$. Superconducting La$_4$H$_{23}$ was obtained by laser heating of LaH$_3$ with ammonia borane at about 120 GPa. Transport measurements reveal the maximum critical temperature $\textit{T}$$_{C}$(onset) = 105 K and the critical field $\textit{H}$$_{C2}$(0) = 32 T at 118 GPa, as evidenced by the sharp drop of electrical resistance and the displacement of superconducting transitions in applied magnetic fields. Moreover, we provide evidence for unconventional transport associated with a pseudogap phase in La$_4$H$_{23}$ using pulsed magnetic fields up to 68 T. A large negative magnetoresistance in the non-superconducting state below 40 K, quasi $\textit{T}$-linear electrical resistance, and a sign-change of its temperature dependence mark the emergence of pseudogap in this hydride. Discovered lanthanum hydride is a new member of the A15 family of superconductors with $\textit{T}$$_C$ exceeding the boiling point of liquid nitrogen.
title Large negative magnetoresistance and pseudogap phase in superconducting A15-type La$_4$H$_{23}$
topic Superconductivity
Materials Science
url https://arxiv.org/abs/2307.13067