On the kinetic description of the objective molecular dynamics

Fuente: arXiv
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Autori principali: James, Richard D., Qi, Kunlun, Wang, Li
Natura: Preprint
Pubblicazione: 2023
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author James, Richard D.
Qi, Kunlun
Wang, Li
author_facet James, Richard D.
Qi, Kunlun
Wang, Li
contents In this paper, we develop a multiscale hierarchy framework for objective molecular dynamics (OMD), a reduced order molecular dynamics with a certain symmetry, that connects it to the statistical kinetic equation, and the macroscopic hydrodynamic model. In the mesoscopic regime, we exploit two interaction scalings that lead, respectively, to either a mean-field type or to a Boltzmann type equation. It turns out that, under the special symmetry of OMD, the mean-field scaling results in vastly simplified dynamics that extinguishes the underlying molecular interaction rule, whereas the Boltzmann scaling yields a meaningful reduced model called the homo-energetic Boltzmann equation. At the macroscopic level, we derive the corresponding Euler and Navier-Stokes systems by conducting a detailed asymptotic analysis. The symmetry again significantly reduces the complexity of the resulting hydrodynamic systems.
format Preprint
id arxiv_https___arxiv_org_abs_2307_16814
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle On the kinetic description of the objective molecular dynamics
James, Richard D.
Qi, Kunlun
Wang, Li
Analysis of PDEs
Mathematical Physics
In this paper, we develop a multiscale hierarchy framework for objective molecular dynamics (OMD), a reduced order molecular dynamics with a certain symmetry, that connects it to the statistical kinetic equation, and the macroscopic hydrodynamic model. In the mesoscopic regime, we exploit two interaction scalings that lead, respectively, to either a mean-field type or to a Boltzmann type equation. It turns out that, under the special symmetry of OMD, the mean-field scaling results in vastly simplified dynamics that extinguishes the underlying molecular interaction rule, whereas the Boltzmann scaling yields a meaningful reduced model called the homo-energetic Boltzmann equation. At the macroscopic level, we derive the corresponding Euler and Navier-Stokes systems by conducting a detailed asymptotic analysis. The symmetry again significantly reduces the complexity of the resulting hydrodynamic systems.
title On the kinetic description of the objective molecular dynamics
topic Analysis of PDEs
Mathematical Physics
url https://arxiv.org/abs/2307.16814