Adsorption superlattice stabilized by elastic interactions in a soft porous crystal
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arXiv
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| Autores principales: | , |
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| Formato: | Preprint |
| Publicado: |
2023
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| _version_ | 1866914721336131584 |
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| author | Mitsumoto, Kota Takae, Kyohei |
| author_facet | Mitsumoto, Kota Takae, Kyohei |
| contents | We numerically show that molecules adsorbed in a soft porous crystal form a superlattice (SL) stabilized by elastic interactions. In a mechanically flexible honeycomb lattice model, when the elastic interactions between the next nearest neighboring lattice sites are strong, a long-range ordered 1/3-filling SL state emerges. By calculating the thermodynamic stability, it is found that the SL state is robust against thermal fluctuation. Our results provide a mechanism of elasticity-driven SL formation, which can be utilized for controlling the distribution of adsorbed molecules. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2308_04651 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Adsorption superlattice stabilized by elastic interactions in a soft porous crystal Mitsumoto, Kota Takae, Kyohei Soft Condensed Matter Statistical Mechanics We numerically show that molecules adsorbed in a soft porous crystal form a superlattice (SL) stabilized by elastic interactions. In a mechanically flexible honeycomb lattice model, when the elastic interactions between the next nearest neighboring lattice sites are strong, a long-range ordered 1/3-filling SL state emerges. By calculating the thermodynamic stability, it is found that the SL state is robust against thermal fluctuation. Our results provide a mechanism of elasticity-driven SL formation, which can be utilized for controlling the distribution of adsorbed molecules. |
| title | Adsorption superlattice stabilized by elastic interactions in a soft porous crystal |
| topic | Soft Condensed Matter Statistical Mechanics |
| url | https://arxiv.org/abs/2308.04651 |