Robust Tensor Hypercontraction of the Particle-Particle Ladder Term in Equation-of-Motion Coupled Cluster Theory
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| Format: | Preprint |
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2023
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| author | Datar, Avdhoot Matthews, Devin A. |
| author_facet | Datar, Avdhoot Matthews, Devin A. |
| contents | One method of representing a high-rank tensor as a (hyper-)product of lower-rank tensors is the tensor hypercontraction (THC) method of Hohenstein et al. This strategy has been found to be useful for reducing the polynomial scaling of coupled-cluster methods by representation of a four dimensional tensor of electron-repulsion integrals in terms of five two-dimensional matrices. Pierce et al. have already shown that the application of a robust form of THC to the particle-particle ladder term (PPL) reduces the cost of this term in couple-cluster singles and doubles (CCSD) from $\mathcal{O} (N^6)$ to $\mathcal{O} (N^5)$ with negligible errors in energy with respect to the density-fitted variant. In this work we have implemented the least-squares variant of THC (LS-THC) which does not require a non-linear tensor factorization, including the robust form (R-LS-THC), for the calculation of the excitation and electron attachment energies using equation-of-motion coupled cluster methods EOMEE-CCSD and EOMEA-CCSD, respectively. We have benchmarked the effect of the R-LS-THC-PPL approximation on excitation energies using the comprehensive QUEST database and the accuracy of electron attachment energies using the NAB22 database. We find that errors on the order of 1 meV are achievable with a reduction in total calculation time of approximately $5\times$. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2308_07569 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Robust Tensor Hypercontraction of the Particle-Particle Ladder Term in Equation-of-Motion Coupled Cluster Theory Datar, Avdhoot Matthews, Devin A. Chemical Physics One method of representing a high-rank tensor as a (hyper-)product of lower-rank tensors is the tensor hypercontraction (THC) method of Hohenstein et al. This strategy has been found to be useful for reducing the polynomial scaling of coupled-cluster methods by representation of a four dimensional tensor of electron-repulsion integrals in terms of five two-dimensional matrices. Pierce et al. have already shown that the application of a robust form of THC to the particle-particle ladder term (PPL) reduces the cost of this term in couple-cluster singles and doubles (CCSD) from $\mathcal{O} (N^6)$ to $\mathcal{O} (N^5)$ with negligible errors in energy with respect to the density-fitted variant. In this work we have implemented the least-squares variant of THC (LS-THC) which does not require a non-linear tensor factorization, including the robust form (R-LS-THC), for the calculation of the excitation and electron attachment energies using equation-of-motion coupled cluster methods EOMEE-CCSD and EOMEA-CCSD, respectively. We have benchmarked the effect of the R-LS-THC-PPL approximation on excitation energies using the comprehensive QUEST database and the accuracy of electron attachment energies using the NAB22 database. We find that errors on the order of 1 meV are achievable with a reduction in total calculation time of approximately $5\times$. |
| title | Robust Tensor Hypercontraction of the Particle-Particle Ladder Term in Equation-of-Motion Coupled Cluster Theory |
| topic | Chemical Physics |
| url | https://arxiv.org/abs/2308.07569 |