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Auteurs principaux: Imai, Takashi, Wang, Jiaming, Smaha, Rebecca W., He, Wei, Wen, Jiajia, Lee, Young S.
Format: Preprint
Publié: 2023
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Accès en ligne:https://arxiv.org/abs/2308.08624
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author Imai, Takashi
Wang, Jiaming
Smaha, Rebecca W.
He, Wei
Wen, Jiajia
Lee, Young S.
author_facet Imai, Takashi
Wang, Jiaming
Smaha, Rebecca W.
He, Wei
Wen, Jiajia
Lee, Young S.
contents We report $^{79}$Br and $^{63}$Cu nuclear quadrupole resonance (NQR) in the paramagnetic state above $T_\text{N} = 15$ K of the antiferromagnetic orthorhombic phase of barlowite Cu$_4$(OD)$_6$FBr consisting of a layered kagome structure. The divergent behavior of the longitudinal $^{79}(1/T_{1})$ and transverse $^{79}(1/T_{2})$ relaxation rates observed at $^{79}$Br sites evidences that critical slowing down of Cu spin fluctuations sets in below $\sim20$ K. This means that one or more Cu sites, most likely at the interlayer Cu(3,4,5) sites between the kagome planes, undergo the antiferromagnetic phase transition in a fairly conventional way. On the other hand, the $^{63}$Cu NQR signal intensity is gradually wiped out below $\sim30$ K, pointing toward gradual spin freezing of the kagome layers instead. These contrasting findings suggest significant roles played by magnetic frustration effects within the kagome layers.
format Preprint
id arxiv_https___arxiv_org_abs_2308_08624
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Local probe investigation of the spin dynamics in the kagome and inter-layers of orthorhombic barlowite Cu$_4$(OD)$_6$FBr: $^{79}$Br and $^{63}$Cu NQR study
Imai, Takashi
Wang, Jiaming
Smaha, Rebecca W.
He, Wei
Wen, Jiajia
Lee, Young S.
Strongly Correlated Electrons
We report $^{79}$Br and $^{63}$Cu nuclear quadrupole resonance (NQR) in the paramagnetic state above $T_\text{N} = 15$ K of the antiferromagnetic orthorhombic phase of barlowite Cu$_4$(OD)$_6$FBr consisting of a layered kagome structure. The divergent behavior of the longitudinal $^{79}(1/T_{1})$ and transverse $^{79}(1/T_{2})$ relaxation rates observed at $^{79}$Br sites evidences that critical slowing down of Cu spin fluctuations sets in below $\sim20$ K. This means that one or more Cu sites, most likely at the interlayer Cu(3,4,5) sites between the kagome planes, undergo the antiferromagnetic phase transition in a fairly conventional way. On the other hand, the $^{63}$Cu NQR signal intensity is gradually wiped out below $\sim30$ K, pointing toward gradual spin freezing of the kagome layers instead. These contrasting findings suggest significant roles played by magnetic frustration effects within the kagome layers.
title Local probe investigation of the spin dynamics in the kagome and inter-layers of orthorhombic barlowite Cu$_4$(OD)$_6$FBr: $^{79}$Br and $^{63}$Cu NQR study
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2308.08624