Phantom chain simulations for fracture of polymer networks created from star polymer mixtures of different functionalities
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arXiv
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| Natura: | Preprint |
| Pubblicazione: |
2023
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| _version_ | 1866916286547623936 |
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| author | Masubuchi, Yuichi |
| author_facet | Masubuchi, Yuichi |
| contents | Fujiyabu et al. have experimentally reported that mixing of 3-arm star prepolymers into 4-arm analog improves the toughness of the resultant polymer networks compared to the base network composed of 4-arm star polymers only. For the mechanism of this phenomenon, this study conducted phantom chain simulations for polymer networks composed of mixtures of star branch prepolymers with equal arm length and different arm numbers, (f_1,f_2 )=(3,4), (3,6) and (3,8), for various f_1=3 prepolymer fractions ϕ_3. The networks were created via end-linking reactions between prepolymers traced by a Brownian dynamics scheme, and the network structure was stored at different conversion ratios ϕ_c, ranging from 0.6 and 0.9. The cycle rank of the gelated networks ξ is fully consistent with the mean field theory, demonstrating that the examined network structure is statistically fair. The networks were stretched with energy minimization until the break, and fracture characteristics including strain at break ε_b, stress at break σ_b, work for fracture W_b, and the ratio of broken strands ϕ_bb, were obtained. ε_b, σ_b/ϕ_bb, and W_b/ϕ_bb data plotted against ξ roughly follow the master curves reported for the base networks without mixing, implying that the change of fracture properties by the mixing of f_1=3 mainly corresponds to a decrease of ξ. The mixing slightly suppresses σ_b/ϕ_bb and W_b/ϕ_bb for large f_2 cases compared to the base networks because of a biased breakage at the network strands without extenders, which are prepolymers with only two reacted arms. The analysis for broken strands exhibited a new master curve for the ξ-dependence of the molecular weight of broken strands. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2310_16282 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Phantom chain simulations for fracture of polymer networks created from star polymer mixtures of different functionalities Masubuchi, Yuichi Soft Condensed Matter Fujiyabu et al. have experimentally reported that mixing of 3-arm star prepolymers into 4-arm analog improves the toughness of the resultant polymer networks compared to the base network composed of 4-arm star polymers only. For the mechanism of this phenomenon, this study conducted phantom chain simulations for polymer networks composed of mixtures of star branch prepolymers with equal arm length and different arm numbers, (f_1,f_2 )=(3,4), (3,6) and (3,8), for various f_1=3 prepolymer fractions ϕ_3. The networks were created via end-linking reactions between prepolymers traced by a Brownian dynamics scheme, and the network structure was stored at different conversion ratios ϕ_c, ranging from 0.6 and 0.9. The cycle rank of the gelated networks ξ is fully consistent with the mean field theory, demonstrating that the examined network structure is statistically fair. The networks were stretched with energy minimization until the break, and fracture characteristics including strain at break ε_b, stress at break σ_b, work for fracture W_b, and the ratio of broken strands ϕ_bb, were obtained. ε_b, σ_b/ϕ_bb, and W_b/ϕ_bb data plotted against ξ roughly follow the master curves reported for the base networks without mixing, implying that the change of fracture properties by the mixing of f_1=3 mainly corresponds to a decrease of ξ. The mixing slightly suppresses σ_b/ϕ_bb and W_b/ϕ_bb for large f_2 cases compared to the base networks because of a biased breakage at the network strands without extenders, which are prepolymers with only two reacted arms. The analysis for broken strands exhibited a new master curve for the ξ-dependence of the molecular weight of broken strands. |
| title | Phantom chain simulations for fracture of polymer networks created from star polymer mixtures of different functionalities |
| topic | Soft Condensed Matter |
| url | https://arxiv.org/abs/2310.16282 |