Macroscopically Self-Aligned and Chiralized Carbon Nanotubes: From Filtration to Innovation

Fuente: arXiv
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Main Authors: Doumani, Jacques, Zahn, Keshav, Yu, Shengjie, Barrios, Gustavo Rodriguez, Sasmal, Somesh, Kikuchi, Rikuta, Kritzell, T. Elijah, Xu, Hongjing, Baydin, Andrey, Kono, Junichiro
Format: Preprint
Published: 2023
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author Doumani, Jacques
Zahn, Keshav
Yu, Shengjie
Barrios, Gustavo Rodriguez
Sasmal, Somesh
Kikuchi, Rikuta
Kritzell, T. Elijah
Xu, Hongjing
Baydin, Andrey
Kono, Junichiro
author_facet Doumani, Jacques
Zahn, Keshav
Yu, Shengjie
Barrios, Gustavo Rodriguez
Sasmal, Somesh
Kikuchi, Rikuta
Kritzell, T. Elijah
Xu, Hongjing
Baydin, Andrey
Kono, Junichiro
contents Because of their natural one-dimensional (1D) structure combined with intricate chiral variations, carbon nanotubes (CNTs) exhibit various exceptional physical properties, such as ultrahigh electrical and thermal conductivity, exceptional mechanical strength, and chirality-dependent metallicity. These properties make CNTs highly promising for diverse applications, including field-effect transistors, sensors, photodetectors, and thermoelectric devices. While CNTs excel individually at the nanoscale, their 1D and chiral nature can be lost on a macroscopic scale when they are randomly assembled. Therefore, the alignment and organization of CNTs in macroscopic structures is crucial for harnessing their full potential. In this review, we explore recent advancements in understanding CNT alignment mechanisms, improving CNT aligning methods, and demonstrating macroscopically 1D properties of ordered CNT assemblies. We also focus on a newly discovered class of CNT architectures, combining CNT alignment and twisting mechanisms to create artificial radial and chiral CNT films at wafer scales. Finally, we summarize recent developments related to aligned and chiral CNT films in optoelectronics, highlighting their unique roles in solar cells, thermal emitters, and optical modulators.
format Preprint
id arxiv_https___arxiv_org_abs_2312_00984
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Macroscopically Self-Aligned and Chiralized Carbon Nanotubes: From Filtration to Innovation
Doumani, Jacques
Zahn, Keshav
Yu, Shengjie
Barrios, Gustavo Rodriguez
Sasmal, Somesh
Kikuchi, Rikuta
Kritzell, T. Elijah
Xu, Hongjing
Baydin, Andrey
Kono, Junichiro
Applied Physics
Materials Science
Optics
Because of their natural one-dimensional (1D) structure combined with intricate chiral variations, carbon nanotubes (CNTs) exhibit various exceptional physical properties, such as ultrahigh electrical and thermal conductivity, exceptional mechanical strength, and chirality-dependent metallicity. These properties make CNTs highly promising for diverse applications, including field-effect transistors, sensors, photodetectors, and thermoelectric devices. While CNTs excel individually at the nanoscale, their 1D and chiral nature can be lost on a macroscopic scale when they are randomly assembled. Therefore, the alignment and organization of CNTs in macroscopic structures is crucial for harnessing their full potential. In this review, we explore recent advancements in understanding CNT alignment mechanisms, improving CNT aligning methods, and demonstrating macroscopically 1D properties of ordered CNT assemblies. We also focus on a newly discovered class of CNT architectures, combining CNT alignment and twisting mechanisms to create artificial radial and chiral CNT films at wafer scales. Finally, we summarize recent developments related to aligned and chiral CNT films in optoelectronics, highlighting their unique roles in solar cells, thermal emitters, and optical modulators.
title Macroscopically Self-Aligned and Chiralized Carbon Nanotubes: From Filtration to Innovation
topic Applied Physics
Materials Science
Optics
url https://arxiv.org/abs/2312.00984