Electric Double Layer from Phase Demixing Reinforced by Strong Coupling Electrostatics
Fuente:
arXiv
Enregistré dans:
| Auteurs principaux: | , , , , |
|---|---|
| Format: | Preprint |
| Publié: |
2023
|
| Sujets: | |
| Accès en ligne: | |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
| _version_ | 1866910284746063872 |
|---|---|
| author | Lee, YeongKyu Cho, JunBeom Lee, Yongkyu Lee, Won Bo Jho, YongSeok |
| author_facet | Lee, YeongKyu Cho, JunBeom Lee, Yongkyu Lee, Won Bo Jho, YongSeok |
| contents | Ionic liquids (ILs) are appealing electrolytes for their favorable physicochemical properties. However, despite their longstanding use, understanding the capacitive behavior of ILs remains challenging. This is largely due to the formation of a non-conventional electric double layer (EDL) at the electrode-electrolyte interface. This study shows that the short-range Yukawa interactions, representing the large anisotropically charged ILs, demix IL to create a spontaneous surface charge separation, which is reinforced by the strongly coupled charge interaction. The properties of the condensed layer, the onset of charge separation, and the rise of overscreening and crowding critically depend on the asymmetry of Yukawa interactions. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2401_00116 |
| institution | arXiv |
| publishDate | 2023 |
| record_format | arxiv |
| spellingShingle | Electric Double Layer from Phase Demixing Reinforced by Strong Coupling Electrostatics Lee, YeongKyu Cho, JunBeom Lee, Yongkyu Lee, Won Bo Jho, YongSeok Soft Condensed Matter Ionic liquids (ILs) are appealing electrolytes for their favorable physicochemical properties. However, despite their longstanding use, understanding the capacitive behavior of ILs remains challenging. This is largely due to the formation of a non-conventional electric double layer (EDL) at the electrode-electrolyte interface. This study shows that the short-range Yukawa interactions, representing the large anisotropically charged ILs, demix IL to create a spontaneous surface charge separation, which is reinforced by the strongly coupled charge interaction. The properties of the condensed layer, the onset of charge separation, and the rise of overscreening and crowding critically depend on the asymmetry of Yukawa interactions. |
| title | Electric Double Layer from Phase Demixing Reinforced by Strong Coupling Electrostatics |
| topic | Soft Condensed Matter |
| url | https://arxiv.org/abs/2401.00116 |