Kagomerization of transition metal monolayers induced by two-dimensional hexagonal boron nitride

Fuente: arXiv
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Autori principali: Zhou, Hangyu, Dias, Manuel dos Santos, Zhang, Youguang, Zhao, Weisheng, Lounis, Samir
Natura: Preprint
Pubblicazione: 2023
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author Zhou, Hangyu
Dias, Manuel dos Santos
Zhang, Youguang
Zhao, Weisheng
Lounis, Samir
author_facet Zhou, Hangyu
Dias, Manuel dos Santos
Zhang, Youguang
Zhao, Weisheng
Lounis, Samir
contents The kagome lattice is an exciting solid state physics platform for the emergence of nontrivial quantum states driven by electronic correlations: topological effects, unconventional superconductivity, charge and spin density waves, and unusual magnetic states such as quantum spin liquids. While kagome lattices have been realized in complex multi-atomic bulk compounds, here we demonstrate from first-principles a process that we dub kagomerization, in which we fabricate a two-dimensional kagome lattice in monolayers of transition metals utilizing a hexagonal boron nitride (h-BN) overlayer. Surprisingly, h-BN induces a large rearrangement of the transition metal atoms supported on a fcc(111) heavy-metal surface. This reconstruction is found to be rather generic for this type of heterostructures and has a profound impact on the underlying magnetic properties, ultimately stabilizing various topological magnetic solitons such as skyrmions and bimerons. Our findings call for a reconsideration of h-BN as merely a passive capping layer, showing its potential for not only reconstructing the atomic structure of the underlying material, e.g. through the kagomerization of magnetic films, but also enabling electronic and magnetic phases that are highly sought for the next generation of device technologies.
format Preprint
id arxiv_https___arxiv_org_abs_2401_00516
institution arXiv
publishDate 2023
record_format arxiv
spellingShingle Kagomerization of transition metal monolayers induced by two-dimensional hexagonal boron nitride
Zhou, Hangyu
Dias, Manuel dos Santos
Zhang, Youguang
Zhao, Weisheng
Lounis, Samir
Materials Science
The kagome lattice is an exciting solid state physics platform for the emergence of nontrivial quantum states driven by electronic correlations: topological effects, unconventional superconductivity, charge and spin density waves, and unusual magnetic states such as quantum spin liquids. While kagome lattices have been realized in complex multi-atomic bulk compounds, here we demonstrate from first-principles a process that we dub kagomerization, in which we fabricate a two-dimensional kagome lattice in monolayers of transition metals utilizing a hexagonal boron nitride (h-BN) overlayer. Surprisingly, h-BN induces a large rearrangement of the transition metal atoms supported on a fcc(111) heavy-metal surface. This reconstruction is found to be rather generic for this type of heterostructures and has a profound impact on the underlying magnetic properties, ultimately stabilizing various topological magnetic solitons such as skyrmions and bimerons. Our findings call for a reconsideration of h-BN as merely a passive capping layer, showing its potential for not only reconstructing the atomic structure of the underlying material, e.g. through the kagomerization of magnetic films, but also enabling electronic and magnetic phases that are highly sought for the next generation of device technologies.
title Kagomerization of transition metal monolayers induced by two-dimensional hexagonal boron nitride
topic Materials Science
url https://arxiv.org/abs/2401.00516