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Bibliographic Details
Main Authors: Shin, Dong-Ho, Yang, Jun, Mukherjee, Samik, Bahrami, Amin, Lehmann, Sebastian, Nasiri, Noushin, Krahl, Fabian, Pang, Chi, Wrzesińska-Lashkova, Angelika, Vaynzof, Yana, Wohlrab, Steve, Popov, Alexey, Nielsch, Kornelius
Format: Preprint
Published: 2024
Subjects:
Online Access:https://arxiv.org/abs/2401.07607
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author Shin, Dong-Ho
Yang, Jun
Mukherjee, Samik
Bahrami, Amin
Lehmann, Sebastian
Nasiri, Noushin
Krahl, Fabian
Pang, Chi
Wrzesińska-Lashkova, Angelika
Vaynzof, Yana
Wohlrab, Steve
Popov, Alexey
Nielsch, Kornelius
author_facet Shin, Dong-Ho
Yang, Jun
Mukherjee, Samik
Bahrami, Amin
Lehmann, Sebastian
Nasiri, Noushin
Krahl, Fabian
Pang, Chi
Wrzesińska-Lashkova, Angelika
Vaynzof, Yana
Wohlrab, Steve
Popov, Alexey
Nielsch, Kornelius
contents SnS2 stands out as a highly promising two-dimensional material with significant potential for applications in the field of electronics. Numerous attempts have been undertaken to modulate the physical properties of SnS2 by doping with various metal ions. Here, we deposited a series of Sb-doped SnS2 via atomic layer deposition (ALD) super-cycle process and compared its crystallinity, composition, and optical properties to those of pristine SnS2. We found that the increase in the concentration of Sb is accompanied by a gradual reduction in the Sn and S binding energies. The work function is increased upon Sb doping from 4.32 eV (SnS2) to 4.75 eV (Sb-doped SnS2 with 9:1 ratio). When integrated into photodetectors, the Sb-doped SnS2 showed improved performances, demonstrating increased peak photoresponsivity values from 19.5 A/W to 27.8 A/W at 405 nm, accompanied by an improvement in response speed. These results offer valuable insights into next-generation optoelectronic applications based on SnS2.
format Preprint
id arxiv_https___arxiv_org_abs_2401_07607
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle SnS2 thin film with in-situ and controllable Sb doping via atomic layer deposition for optoelectronic applications
Shin, Dong-Ho
Yang, Jun
Mukherjee, Samik
Bahrami, Amin
Lehmann, Sebastian
Nasiri, Noushin
Krahl, Fabian
Pang, Chi
Wrzesińska-Lashkova, Angelika
Vaynzof, Yana
Wohlrab, Steve
Popov, Alexey
Nielsch, Kornelius
Materials Science
SnS2 stands out as a highly promising two-dimensional material with significant potential for applications in the field of electronics. Numerous attempts have been undertaken to modulate the physical properties of SnS2 by doping with various metal ions. Here, we deposited a series of Sb-doped SnS2 via atomic layer deposition (ALD) super-cycle process and compared its crystallinity, composition, and optical properties to those of pristine SnS2. We found that the increase in the concentration of Sb is accompanied by a gradual reduction in the Sn and S binding energies. The work function is increased upon Sb doping from 4.32 eV (SnS2) to 4.75 eV (Sb-doped SnS2 with 9:1 ratio). When integrated into photodetectors, the Sb-doped SnS2 showed improved performances, demonstrating increased peak photoresponsivity values from 19.5 A/W to 27.8 A/W at 405 nm, accompanied by an improvement in response speed. These results offer valuable insights into next-generation optoelectronic applications based on SnS2.
title SnS2 thin film with in-situ and controllable Sb doping via atomic layer deposition for optoelectronic applications
topic Materials Science
url https://arxiv.org/abs/2401.07607