Noncollinear electric dipoles in a polar, chiral phase of CsSnBr$_3$ perovskite
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| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Preprint |
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2024
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| _version_ | 1866909989990301696 |
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| author | Fabini, Douglas H. Honasoge, Kedar Cohen, Adi Bette, Sebastian McCall, Kyle M. Stoumpos, Constantinos C. Klenner, Steffen Zipkat, Mirjam Hoang, Le Phuong Nuss, Jürgen Kremer, Reinhard K. Kanatzidis, Mercouri G. Yaffe, Omer Kaiser, Stefan Lotsch, Bettina V. |
| author_facet | Fabini, Douglas H. Honasoge, Kedar Cohen, Adi Bette, Sebastian McCall, Kyle M. Stoumpos, Constantinos C. Klenner, Steffen Zipkat, Mirjam Hoang, Le Phuong Nuss, Jürgen Kremer, Reinhard K. Kanatzidis, Mercouri G. Yaffe, Omer Kaiser, Stefan Lotsch, Bettina V. |
| contents | Polar and chiral crystal symmetries confer a variety of potentially useful functionalities upon solids by coupling otherwise noninteracting mechanical, electronic, optical, and magnetic degrees of freedom. We describe two unstudied phases of the 3D perovskite, CsSnBr$_3$, which emerge below 85 K due to the formation of Sn(II) lone pairs and their interaction with extant octahedral tilts. Phase II (77 K<$T$<85 K, space group $P2_1/m$) exhibits ferroaxial order driven by a noncollinear pattern of lone pair-driven distortions within the plane normal to the unique octahedral tilt axis, preserving the inversion symmetry observed at higher temperatures. Phase I ($T$<77 K, space group $P2_1$) additionally exhibits ferroelectric order due to distortions along the unique tilt axis, breaking both inversion and mirror symmetries. This polar and chiral phase exhibits second harmonic generation from the bulk and a large, intrinsic polarization$-$electrostriction coefficient along the polar axis ($Q_{22}\approx$1.1 m$^4$ C$^{-2}$), resulting in acute negative thermal expansion ($α_V=-9\times10^{-5}$ K$^{-1}$) through the onset of spontaneous polarization. The unprecedented structures of phases I and II were predicted by recursively following harmonic phonon instabilities to generate a tree of candidate structures and subsequently corroborated by synchrotron X-ray powder diffraction and polarized Raman and $^{81}$Br nuclear quadrupole resonance spectroscopies. Relativistic electronic structure scenarios compatible with reported photoluminescence measurements are discussed. Together, the polar symmetry, small bandgap, large spin-orbit splitting of Sn 5$p$ orbitals, and predicted strain sensitivity of the symmetry-breaking distortions suggest bulk samples and epitaxial films of CsSnBr$_3$ or its neighboring solid solutions as strong candidates for bulk Rashba effects. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2401_07978 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Noncollinear electric dipoles in a polar, chiral phase of CsSnBr$_3$ perovskite Fabini, Douglas H. Honasoge, Kedar Cohen, Adi Bette, Sebastian McCall, Kyle M. Stoumpos, Constantinos C. Klenner, Steffen Zipkat, Mirjam Hoang, Le Phuong Nuss, Jürgen Kremer, Reinhard K. Kanatzidis, Mercouri G. Yaffe, Omer Kaiser, Stefan Lotsch, Bettina V. Materials Science Polar and chiral crystal symmetries confer a variety of potentially useful functionalities upon solids by coupling otherwise noninteracting mechanical, electronic, optical, and magnetic degrees of freedom. We describe two unstudied phases of the 3D perovskite, CsSnBr$_3$, which emerge below 85 K due to the formation of Sn(II) lone pairs and their interaction with extant octahedral tilts. Phase II (77 K<$T$<85 K, space group $P2_1/m$) exhibits ferroaxial order driven by a noncollinear pattern of lone pair-driven distortions within the plane normal to the unique octahedral tilt axis, preserving the inversion symmetry observed at higher temperatures. Phase I ($T$<77 K, space group $P2_1$) additionally exhibits ferroelectric order due to distortions along the unique tilt axis, breaking both inversion and mirror symmetries. This polar and chiral phase exhibits second harmonic generation from the bulk and a large, intrinsic polarization$-$electrostriction coefficient along the polar axis ($Q_{22}\approx$1.1 m$^4$ C$^{-2}$), resulting in acute negative thermal expansion ($α_V=-9\times10^{-5}$ K$^{-1}$) through the onset of spontaneous polarization. The unprecedented structures of phases I and II were predicted by recursively following harmonic phonon instabilities to generate a tree of candidate structures and subsequently corroborated by synchrotron X-ray powder diffraction and polarized Raman and $^{81}$Br nuclear quadrupole resonance spectroscopies. Relativistic electronic structure scenarios compatible with reported photoluminescence measurements are discussed. Together, the polar symmetry, small bandgap, large spin-orbit splitting of Sn 5$p$ orbitals, and predicted strain sensitivity of the symmetry-breaking distortions suggest bulk samples and epitaxial films of CsSnBr$_3$ or its neighboring solid solutions as strong candidates for bulk Rashba effects. |
| title | Noncollinear electric dipoles in a polar, chiral phase of CsSnBr$_3$ perovskite |
| topic | Materials Science |
| url | https://arxiv.org/abs/2401.07978 |