Resolution dependence of most probable pathways with state-dependent diffusivity

Fuente: arXiv
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Autori principali: Thorneywork, Alice L., Gladrow, Jannes, Keyser, Ulrich F., Cates, Michael E., Adhikari, Ronojoy, Kappler, Julian
Natura: Preprint
Pubblicazione: 2024
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author Thorneywork, Alice L.
Gladrow, Jannes
Keyser, Ulrich F.
Cates, Michael E.
Adhikari, Ronojoy
Kappler, Julian
author_facet Thorneywork, Alice L.
Gladrow, Jannes
Keyser, Ulrich F.
Cates, Michael E.
Adhikari, Ronojoy
Kappler, Julian
contents Recent experiments have probed the relative likelihoods of trajectories in stochastic systems by observing survival probabilities within a tube of radius $R$ in spacetime. We measure such probabilities here for a colloidal particle in a corrugated channel, corresponding to a bistable potential with state-dependent diffusivity. In contrast to previous findings for state-independent noise, we find that the most probable pathway changes qualitatively as the tube radius $R$ is altered. We explain this by computing the survival probabilities predicted by overdamped Langevin dynamics. At high enough resolution (small enough $R$), survival probabilities depend solely on diffusivity variations, independent of deterministic forces; finite $R$ corrections yield a generalization of the Onsager-Machlup action. As corollary, ratios of survival probabilities are singular as $R \to 0$, but become regular, and described by the classical Onsager-Machlup action, only in the special case of state-independent noise.
format Preprint
id arxiv_https___arxiv_org_abs_2402_01559
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Resolution dependence of most probable pathways with state-dependent diffusivity
Thorneywork, Alice L.
Gladrow, Jannes
Keyser, Ulrich F.
Cates, Michael E.
Adhikari, Ronojoy
Kappler, Julian
Statistical Mechanics
Mesoscale and Nanoscale Physics
Soft Condensed Matter
Chemical Physics
Recent experiments have probed the relative likelihoods of trajectories in stochastic systems by observing survival probabilities within a tube of radius $R$ in spacetime. We measure such probabilities here for a colloidal particle in a corrugated channel, corresponding to a bistable potential with state-dependent diffusivity. In contrast to previous findings for state-independent noise, we find that the most probable pathway changes qualitatively as the tube radius $R$ is altered. We explain this by computing the survival probabilities predicted by overdamped Langevin dynamics. At high enough resolution (small enough $R$), survival probabilities depend solely on diffusivity variations, independent of deterministic forces; finite $R$ corrections yield a generalization of the Onsager-Machlup action. As corollary, ratios of survival probabilities are singular as $R \to 0$, but become regular, and described by the classical Onsager-Machlup action, only in the special case of state-independent noise.
title Resolution dependence of most probable pathways with state-dependent diffusivity
topic Statistical Mechanics
Mesoscale and Nanoscale Physics
Soft Condensed Matter
Chemical Physics
url https://arxiv.org/abs/2402.01559