Ultrafast Nuclear Dynamics in Double-Core Ionized Water Molecules

Fuente: arXiv
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Hauptverfasser: Ismail, Iyas, Inhester, Ludger, Marchenko, Tatiana, Trinter, Florian, Verma, Abhishek, De Fanis, Alberto, Ferte, Anthony, Rivas, Daniel E., Peng, Dawei, Koulentianos, Dimitris, Kukk, Edwin, Penent, Francis, Doumy, Gilles, Sansone, Giuseppe, Bozek, John D., Li, Kai, Young, Linda, Ilchen, Markus, Piancastelli, Maria Novella, Meyer, Michael, Velasquez, Nicolas, Travnikova, Oksana, Boll, Rebecca, Guillemin, Renaud, Dorner, Reinhard, Taieb, Richard, Dold, Simon, Carniato, Stephane, Baumann, Thomas M., Mazza, Tommaso, Ovcharenko, Yevheniy, Puttner, Ralph, Simon, Marc
Format: Preprint
Veröffentlicht: 2024
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author Ismail, Iyas
Inhester, Ludger
Marchenko, Tatiana
Trinter, Florian
Verma, Abhishek
De Fanis, Alberto
Ferte, Anthony
Rivas, Daniel E.
Peng, Dawei
Koulentianos, Dimitris
Kukk, Edwin
Penent, Francis
Doumy, Gilles
Sansone, Giuseppe
Bozek, John D.
Li, Kai
Young, Linda
Ilchen, Markus
Piancastelli, Maria Novella
Meyer, Michael
Velasquez, Nicolas
Travnikova, Oksana
Boll, Rebecca
Guillemin, Renaud
Dorner, Reinhard
Taieb, Richard
Dold, Simon
Carniato, Stephane
Baumann, Thomas M.
Mazza, Tommaso
Ovcharenko, Yevheniy
Puttner, Ralph
Simon, Marc
author_facet Ismail, Iyas
Inhester, Ludger
Marchenko, Tatiana
Trinter, Florian
Verma, Abhishek
De Fanis, Alberto
Ferte, Anthony
Rivas, Daniel E.
Peng, Dawei
Koulentianos, Dimitris
Kukk, Edwin
Penent, Francis
Doumy, Gilles
Sansone, Giuseppe
Bozek, John D.
Li, Kai
Young, Linda
Ilchen, Markus
Piancastelli, Maria Novella
Meyer, Michael
Velasquez, Nicolas
Travnikova, Oksana
Boll, Rebecca
Guillemin, Renaud
Dorner, Reinhard
Taieb, Richard
Dold, Simon
Carniato, Stephane
Baumann, Thomas M.
Mazza, Tommaso
Ovcharenko, Yevheniy
Puttner, Ralph
Simon, Marc
contents Double-core-hole (DCH) states in isolated water and heavy water molecules, resulting from the sequential absorption of two x-ray photons, have been investigated. A comparison of the subsequent Auger emission spectra from the two isotopes provides direct evidence of ultrafast nuclear motion during the 1.5 fs lifetime of these DCH states. Our numerical results align well with the experimental data, providing for various DCH states an in-depth study of the dynamics responsible of the observed isotope effect.
format Preprint
id arxiv_https___arxiv_org_abs_2402_02988
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Ultrafast Nuclear Dynamics in Double-Core Ionized Water Molecules
Ismail, Iyas
Inhester, Ludger
Marchenko, Tatiana
Trinter, Florian
Verma, Abhishek
De Fanis, Alberto
Ferte, Anthony
Rivas, Daniel E.
Peng, Dawei
Koulentianos, Dimitris
Kukk, Edwin
Penent, Francis
Doumy, Gilles
Sansone, Giuseppe
Bozek, John D.
Li, Kai
Young, Linda
Ilchen, Markus
Piancastelli, Maria Novella
Meyer, Michael
Velasquez, Nicolas
Travnikova, Oksana
Boll, Rebecca
Guillemin, Renaud
Dorner, Reinhard
Taieb, Richard
Dold, Simon
Carniato, Stephane
Baumann, Thomas M.
Mazza, Tommaso
Ovcharenko, Yevheniy
Puttner, Ralph
Simon, Marc
Chemical Physics
Double-core-hole (DCH) states in isolated water and heavy water molecules, resulting from the sequential absorption of two x-ray photons, have been investigated. A comparison of the subsequent Auger emission spectra from the two isotopes provides direct evidence of ultrafast nuclear motion during the 1.5 fs lifetime of these DCH states. Our numerical results align well with the experimental data, providing for various DCH states an in-depth study of the dynamics responsible of the observed isotope effect.
title Ultrafast Nuclear Dynamics in Double-Core Ionized Water Molecules
topic Chemical Physics
url https://arxiv.org/abs/2402.02988