Symmetry shapes thermodynamics of macroscopic quantum systems

Fuente: arXiv
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Autori principali: Cavina, Vasco, Soret, Ariane, Aslyamov, Timur, Ptaszyński, Krzysztof, Esposito, Massimiliano
Natura: Preprint
Pubblicazione: 2024
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author Cavina, Vasco
Soret, Ariane
Aslyamov, Timur
Ptaszyński, Krzysztof
Esposito, Massimiliano
author_facet Cavina, Vasco
Soret, Ariane
Aslyamov, Timur
Ptaszyński, Krzysztof
Esposito, Massimiliano
contents We derive a systematic approach to the thermodynamics of quantum systems based on the underlying symmetry groups. We show that the entropy of a system can be described in terms of group-theoretical quantities that are largely independent of the details of its density matrix. We apply our technique to generic $N$ identical interacting $d$-level quantum systems. Using permutation invariance, we find that, for large $N$, entropy displays a universal large deviation behavior with a rate function $s(\boldsymbol{x})$ that is completely independent of the microscopic details of the model, but depends only on the size of the irreducible representations of the permutation group $\text{S}_N$. In turn, the partition function is shown to satisfy a large deviation principle with a free energy $f(\boldsymbol{x})=e(\boldsymbol{x})-β^{-1}s(\boldsymbol{x})$, where $e(\boldsymbol{x})$ is a rate function that only depends on the ground state energy of particular subspaces determined by group representation theory. We apply our theory to the transverse-field Curie-Weiss model, a minimal model of phase transition exhibiting an interplay of thermal and quantum fluctuations.
format Preprint
id arxiv_https___arxiv_org_abs_2402_04214
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Symmetry shapes thermodynamics of macroscopic quantum systems
Cavina, Vasco
Soret, Ariane
Aslyamov, Timur
Ptaszyński, Krzysztof
Esposito, Massimiliano
Quantum Physics
Statistical Mechanics
We derive a systematic approach to the thermodynamics of quantum systems based on the underlying symmetry groups. We show that the entropy of a system can be described in terms of group-theoretical quantities that are largely independent of the details of its density matrix. We apply our technique to generic $N$ identical interacting $d$-level quantum systems. Using permutation invariance, we find that, for large $N$, entropy displays a universal large deviation behavior with a rate function $s(\boldsymbol{x})$ that is completely independent of the microscopic details of the model, but depends only on the size of the irreducible representations of the permutation group $\text{S}_N$. In turn, the partition function is shown to satisfy a large deviation principle with a free energy $f(\boldsymbol{x})=e(\boldsymbol{x})-β^{-1}s(\boldsymbol{x})$, where $e(\boldsymbol{x})$ is a rate function that only depends on the ground state energy of particular subspaces determined by group representation theory. We apply our theory to the transverse-field Curie-Weiss model, a minimal model of phase transition exhibiting an interplay of thermal and quantum fluctuations.
title Symmetry shapes thermodynamics of macroscopic quantum systems
topic Quantum Physics
Statistical Mechanics
url https://arxiv.org/abs/2402.04214