Magnetic field-temperature phase diagram of spin-1/2 triangular lattice antiferromagnet KYbSe$_2$

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Main Authors: Lee, Sangyun, Woods, Andrew J., Lee, Minseong, Zhang, Shengzhi, Choi, Eun Sang, Scheie, A. O., Tennant, D. A., Xing, J., Sefat, A. S., Movshovich, R.
Format: Preprint
Published: 2024
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author Lee, Sangyun
Woods, Andrew J.
Lee, Minseong
Zhang, Shengzhi
Choi, Eun Sang
Scheie, A. O.
Tennant, D. A.
Xing, J.
Sefat, A. S.
Movshovich, R.
author_facet Lee, Sangyun
Woods, Andrew J.
Lee, Minseong
Zhang, Shengzhi
Choi, Eun Sang
Scheie, A. O.
Tennant, D. A.
Xing, J.
Sefat, A. S.
Movshovich, R.
contents A quantum spin liquid (QSL) is a state of matter characterized by fractionalized quasiparticle excitations, quantum entanglement, and a lack of long-range magnetic order. However, QSLs have evaded definitive experimental observation. Several Yb$^{3+}$-based triangular lattice antiferromagnets with effective $S$ = $\frac{1}{2}$ have been suggested to stabilize the QSL state as the ground state. Here, we build a comprehensive magnetic temperature phase diagram of a high-quality single crystalline KYbSe$_2$ via heat capacity and magnetocaloric effect down to 30 mK with magnetic field applied along the $a$-axis. At zero magnetic field, we observe the magnetic long-range order at $T_N$ = 0.29 K entering 120 degrees ordered state in heat capacity, consistent with neutron scattering studies. Analysis of the low-temperature ($T$) specific heat ($C$) at zero magnetic field indicates linear $T$-dependence of $C/T$ and a broad hump of $C/T$ in the proximate QSL region above $T_N$. By applying magnetic field, we observe the up-up-down phase with 1/3 magnetization plateau and oblique phases, in addition to two new phases. These observations strongly indicate that while KYbSe$_2$ closely exhibits characteristics resembling an ideal triangular lattice, deviations may exist, such as the effect of the next-nearest-neighbor exchange interaction, calling for careful consideration for spin Hamiltonian modeling. Further investigations into tuning parameters, such as chemical pressure, could potentially induce an intriguing QSL phase in the material.
format Preprint
id arxiv_https___arxiv_org_abs_2402_06788
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Magnetic field-temperature phase diagram of spin-1/2 triangular lattice antiferromagnet KYbSe$_2$
Lee, Sangyun
Woods, Andrew J.
Lee, Minseong
Zhang, Shengzhi
Choi, Eun Sang
Scheie, A. O.
Tennant, D. A.
Xing, J.
Sefat, A. S.
Movshovich, R.
Strongly Correlated Electrons
Materials Science
A quantum spin liquid (QSL) is a state of matter characterized by fractionalized quasiparticle excitations, quantum entanglement, and a lack of long-range magnetic order. However, QSLs have evaded definitive experimental observation. Several Yb$^{3+}$-based triangular lattice antiferromagnets with effective $S$ = $\frac{1}{2}$ have been suggested to stabilize the QSL state as the ground state. Here, we build a comprehensive magnetic temperature phase diagram of a high-quality single crystalline KYbSe$_2$ via heat capacity and magnetocaloric effect down to 30 mK with magnetic field applied along the $a$-axis. At zero magnetic field, we observe the magnetic long-range order at $T_N$ = 0.29 K entering 120 degrees ordered state in heat capacity, consistent with neutron scattering studies. Analysis of the low-temperature ($T$) specific heat ($C$) at zero magnetic field indicates linear $T$-dependence of $C/T$ and a broad hump of $C/T$ in the proximate QSL region above $T_N$. By applying magnetic field, we observe the up-up-down phase with 1/3 magnetization plateau and oblique phases, in addition to two new phases. These observations strongly indicate that while KYbSe$_2$ closely exhibits characteristics resembling an ideal triangular lattice, deviations may exist, such as the effect of the next-nearest-neighbor exchange interaction, calling for careful consideration for spin Hamiltonian modeling. Further investigations into tuning parameters, such as chemical pressure, could potentially induce an intriguing QSL phase in the material.
title Magnetic field-temperature phase diagram of spin-1/2 triangular lattice antiferromagnet KYbSe$_2$
topic Strongly Correlated Electrons
Materials Science
url https://arxiv.org/abs/2402.06788