Line-shape study of CO perturbed by N${_2}$ with mid-infrared frequency comb-based Fourier-transform spectroscopy

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Hauptverfasser: Nishiyama, Akiko, Kowzan, Grzegorz, Charczun, Dominik, Ciuryło, Roman, Coluccelli, Nicola, Masłowski, Piotr
Format: Preprint
Veröffentlicht: 2024
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author Nishiyama, Akiko
Kowzan, Grzegorz
Charczun, Dominik
Ciuryło, Roman
Coluccelli, Nicola
Masłowski, Piotr
author_facet Nishiyama, Akiko
Kowzan, Grzegorz
Charczun, Dominik
Ciuryło, Roman
Coluccelli, Nicola
Masłowski, Piotr
contents We developed a mid-infrared optical frequency comb-based Fourier-transform spectrometer and performed a line-shape study of the fundamental vibrational band of CO perturbed by N${_2}$, which is crucial for atmospheric science and astronomical observations. The comb-based FTS enabled us to measure the whole vibrational band with high resolution and precision at several pressures between 10 and 400 Torr. Observed absorption profiles were fitted with the speed-dependent Voigt profile. Collisional broadening, speed-dependent collisional width and shift coefficients are derived. The reliability of our results is established from considerations of systematic errors and comparison with previous studies.
format Preprint
id arxiv_https___arxiv_org_abs_2402_10509
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Line-shape study of CO perturbed by N${_2}$ with mid-infrared frequency comb-based Fourier-transform spectroscopy
Nishiyama, Akiko
Kowzan, Grzegorz
Charczun, Dominik
Ciuryło, Roman
Coluccelli, Nicola
Masłowski, Piotr
Chemical Physics
Instrumentation and Methods for Astrophysics
We developed a mid-infrared optical frequency comb-based Fourier-transform spectrometer and performed a line-shape study of the fundamental vibrational band of CO perturbed by N${_2}$, which is crucial for atmospheric science and astronomical observations. The comb-based FTS enabled us to measure the whole vibrational band with high resolution and precision at several pressures between 10 and 400 Torr. Observed absorption profiles were fitted with the speed-dependent Voigt profile. Collisional broadening, speed-dependent collisional width and shift coefficients are derived. The reliability of our results is established from considerations of systematic errors and comparison with previous studies.
title Line-shape study of CO perturbed by N${_2}$ with mid-infrared frequency comb-based Fourier-transform spectroscopy
topic Chemical Physics
Instrumentation and Methods for Astrophysics
url https://arxiv.org/abs/2402.10509