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Bibliographische Detailangaben
Hauptverfasser: Amouretti, A., Crépisson, C., Azadi, S., Cabaret, D., Campbell, T., Chin, D. A., Colin, B., Collins, G. R., Crandall, L., Fiquet, G., Forte, A., Gawne, T., Guyot, F., Heighway, P., Lee, H., McGonegle, D., Nagler, B., Pintor, J., Polsin, D., Rousse, G., Shi, Y., Smith, E., Wark, J. S., Vinko, S. M., Harmand, M.
Format: Preprint
Veröffentlicht: 2024
Schlagworte:
Materials Science
Online-Zugang:https://arxiv.org/abs/2402.18432
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Inhaltsangabe:
  • We present in-situ x-ray diffraction and velocity measurements of Fe$_2$O$_3$ under laser shock compression at pressures between 38-116 GPa. None of the phases reported by static compression studies were observed. Instead, we observed an isostructural phase transition from $α$-Fe$_2$O$_3$ to a new $α^\prime$-Fe$_2$O$_3$ phase at a pressure of 50-62 GPa. The $α^\prime$-Fe$_2$O$_3$ phase differs from $α$-Fe$_2$O$_3$ by an 11% volume drop and a different unit cell compressibility. We further observed a two-wave structure in the velocity profile, which can be related to an intermediate regime where both $α$ and $α^\prime$ phases coexist. Density functional theory calculations with a Hubbard parameter indicate that the observed unit cell volume drop can be associated with a spin transition following a magnetic collapse.

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