Work Sum Rule for Open Quantum Systems

Fuente: arXiv
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Autores principales: Kumar, Parth, Webb, Caleb M., Stafford, Charles A.
Formato: Preprint
Publicado: 2024
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author Kumar, Parth
Webb, Caleb M.
Stafford, Charles A.
author_facet Kumar, Parth
Webb, Caleb M.
Stafford, Charles A.
contents A key question in the thermodynamics of open quantum systems is how to partition thermodynamic quantities such as entropy, work, and internal energy between the system and its environment. We show that the only partition under which entropy is nonsingular is based on a partition of Hilbert space, which assigns half the system-environment coupling to the system and half to the environment. However, quantum work partitions nontrivially under Hilbert-space partition, and we derive a work sum rule that accounts for quantum work at a distance. All state functions of the system are shown to be path independent once this nonlocal quantum work is properly accounted for. Our results are illustrated with application to a driven resonant level strongly coupled to a reservoir.
format Preprint
id arxiv_https___arxiv_org_abs_2402_18855
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Work Sum Rule for Open Quantum Systems
Kumar, Parth
Webb, Caleb M.
Stafford, Charles A.
Quantum Physics
Mesoscale and Nanoscale Physics
Statistical Mechanics
A key question in the thermodynamics of open quantum systems is how to partition thermodynamic quantities such as entropy, work, and internal energy between the system and its environment. We show that the only partition under which entropy is nonsingular is based on a partition of Hilbert space, which assigns half the system-environment coupling to the system and half to the environment. However, quantum work partitions nontrivially under Hilbert-space partition, and we derive a work sum rule that accounts for quantum work at a distance. All state functions of the system are shown to be path independent once this nonlocal quantum work is properly accounted for. Our results are illustrated with application to a driven resonant level strongly coupled to a reservoir.
title Work Sum Rule for Open Quantum Systems
topic Quantum Physics
Mesoscale and Nanoscale Physics
Statistical Mechanics
url https://arxiv.org/abs/2402.18855