Impurities, or dopants, that is the question

Fuente: arXiv
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Main Authors: Gault, Baptiste, Aota, Leonardo Shoji, Krämer, Mathias, Kim, Se-Ho
Format: Preprint
Published: 2024
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author Gault, Baptiste
Aota, Leonardo Shoji
Krämer, Mathias
Kim, Se-Ho
author_facet Gault, Baptiste
Aota, Leonardo Shoji
Krämer, Mathias
Kim, Se-Ho
contents The numerous stories around LK-99 as a possible room-temperature superconductor over the summer of 2023 epitomise that materials are more than a bulk crystallographic structure or an expected composition. Like all materials, those at the core of technologies for the energy generation transition, including batteries, catalysts or quantum materials draw their properties from a hierarchy of microstructural features where impurities can dramatically influence the outcomes. As we move towards a circular economy, the recycling of materials will inevitably create fluxes of increasingly impure materials, generating new challenges for fabricating materials with controlled properties. Here, we provide our perspective on how high-end microscopy and microanalysis have helped us to understand relationships between synthesis, processing and microstructure, avoiding imprecise or even erroneous interpretations on the origins of the properties from a range of materials. We highlight examples of how unexpected impurities and their spatial distribution on the nanoscale can be turned into an advantage to define pathways for synthesis of materials with new and novel sets of physical properties.
format Preprint
id arxiv_https___arxiv_org_abs_2403_03480
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Impurities, or dopants, that is the question
Gault, Baptiste
Aota, Leonardo Shoji
Krämer, Mathias
Kim, Se-Ho
Materials Science
The numerous stories around LK-99 as a possible room-temperature superconductor over the summer of 2023 epitomise that materials are more than a bulk crystallographic structure or an expected composition. Like all materials, those at the core of technologies for the energy generation transition, including batteries, catalysts or quantum materials draw their properties from a hierarchy of microstructural features where impurities can dramatically influence the outcomes. As we move towards a circular economy, the recycling of materials will inevitably create fluxes of increasingly impure materials, generating new challenges for fabricating materials with controlled properties. Here, we provide our perspective on how high-end microscopy and microanalysis have helped us to understand relationships between synthesis, processing and microstructure, avoiding imprecise or even erroneous interpretations on the origins of the properties from a range of materials. We highlight examples of how unexpected impurities and their spatial distribution on the nanoscale can be turned into an advantage to define pathways for synthesis of materials with new and novel sets of physical properties.
title Impurities, or dopants, that is the question
topic Materials Science
url https://arxiv.org/abs/2403.03480