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Main Authors: Rocca, Dario, Cortes, Cristian L., Gonthier, Jerome, Ollitrault, Pauline J., Parrish, Robert M., Anselmetti, Gian-Luca, Degroote, Matthias, Moll, Nikolaj, Santagati, Raffaele, Streif, Michael
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2403.03502
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author Rocca, Dario
Cortes, Cristian L.
Gonthier, Jerome
Ollitrault, Pauline J.
Parrish, Robert M.
Anselmetti, Gian-Luca
Degroote, Matthias
Moll, Nikolaj
Santagati, Raffaele
Streif, Michael
author_facet Rocca, Dario
Cortes, Cristian L.
Gonthier, Jerome
Ollitrault, Pauline J.
Parrish, Robert M.
Anselmetti, Gian-Luca
Degroote, Matthias
Moll, Nikolaj
Santagati, Raffaele
Streif, Michael
contents Quantum phase estimation based on qubitization is the state-of-the-art fault-tolerant quantum algorithm for computing ground-state energies in chemical applications. In this context, the 1-norm of the Hamiltonian plays a fundamental role in determining the total number of required iterations and also the overall computational cost. In this work, we introduce the symmetry-compressed double factorization (SCDF) approach, which combines a compressed double factorization of the Hamiltonian with the symmetry shift technique, significantly reducing the 1-norm value. The effectiveness of this approach is demonstrated numerically by considering various benchmark systems, including the FeMoco molecule, cytochrome P450, and hydrogen chains of different sizes. To compare the efficiency of SCDF to other methods in absolute terms, we estimate Toffoli gate requirements, which dominate the execution time on fault-tolerant quantum computers. For the systems considered here, SCDF leads to a sizeable reduction of the Toffoli gate count in comparison to other variants of double factorization or even tensor hypercontraction, which is usually regarded as the most efficient approach for qubitization.
format Preprint
id arxiv_https___arxiv_org_abs_2403_03502
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Reducing the runtime of fault-tolerant quantum simulations in chemistry through symmetry-compressed double factorization
Rocca, Dario
Cortes, Cristian L.
Gonthier, Jerome
Ollitrault, Pauline J.
Parrish, Robert M.
Anselmetti, Gian-Luca
Degroote, Matthias
Moll, Nikolaj
Santagati, Raffaele
Streif, Michael
Quantum Physics
Quantum phase estimation based on qubitization is the state-of-the-art fault-tolerant quantum algorithm for computing ground-state energies in chemical applications. In this context, the 1-norm of the Hamiltonian plays a fundamental role in determining the total number of required iterations and also the overall computational cost. In this work, we introduce the symmetry-compressed double factorization (SCDF) approach, which combines a compressed double factorization of the Hamiltonian with the symmetry shift technique, significantly reducing the 1-norm value. The effectiveness of this approach is demonstrated numerically by considering various benchmark systems, including the FeMoco molecule, cytochrome P450, and hydrogen chains of different sizes. To compare the efficiency of SCDF to other methods in absolute terms, we estimate Toffoli gate requirements, which dominate the execution time on fault-tolerant quantum computers. For the systems considered here, SCDF leads to a sizeable reduction of the Toffoli gate count in comparison to other variants of double factorization or even tensor hypercontraction, which is usually regarded as the most efficient approach for qubitization.
title Reducing the runtime of fault-tolerant quantum simulations in chemistry through symmetry-compressed double factorization
topic Quantum Physics
url https://arxiv.org/abs/2403.03502