Tellurization of Pd(111): absence of PdTe$_2$ but formation of a TePd$_2$ surface alloy

Fuente: arXiv
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Auteurs principaux: Engel, Eric, Wegerich, Alexander, Raabgrund, Andreas, Schneider, M. Alexander
Format: Preprint
Publié: 2024
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author Engel, Eric
Wegerich, Alexander
Raabgrund, Andreas
Schneider, M. Alexander
author_facet Engel, Eric
Wegerich, Alexander
Raabgrund, Andreas
Schneider, M. Alexander
contents In a recent publication [2D Materials, 8, 045033 (2021), arXiv:2103.11403], it was reported that the growth of a monolayer PdTe$_2$ in ultra-high vacuum could be achieved by deposition of tellurium on a palladium (111) crystal surface and subsequent thermal annealing. By means of low-energy electron diffraction intensity (LEED-IV) structural analysis, we show that the obtained $\left(\sqrt{3}\times \sqrt{3} \right)\textrm{R30}^\circ$ superstructure is in fact a TePd$_2$ surface alloy. Attempts to produce a PdTe$_2$ layer in ultra-high vacuum by increasing the Te content on the surface were not successful.
format Preprint
id arxiv_https___arxiv_org_abs_2403_03564
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Tellurization of Pd(111): absence of PdTe$_2$ but formation of a TePd$_2$ surface alloy
Engel, Eric
Wegerich, Alexander
Raabgrund, Andreas
Schneider, M. Alexander
Materials Science
In a recent publication [2D Materials, 8, 045033 (2021), arXiv:2103.11403], it was reported that the growth of a monolayer PdTe$_2$ in ultra-high vacuum could be achieved by deposition of tellurium on a palladium (111) crystal surface and subsequent thermal annealing. By means of low-energy electron diffraction intensity (LEED-IV) structural analysis, we show that the obtained $\left(\sqrt{3}\times \sqrt{3} \right)\textrm{R30}^\circ$ superstructure is in fact a TePd$_2$ surface alloy. Attempts to produce a PdTe$_2$ layer in ultra-high vacuum by increasing the Te content on the surface were not successful.
title Tellurization of Pd(111): absence of PdTe$_2$ but formation of a TePd$_2$ surface alloy
topic Materials Science
url https://arxiv.org/abs/2403.03564