Thiol-amine co-solvents aided direct synthesis of ZnTe thin films by spin coating for low cost optoelectronic applications

Fuente: arXiv
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Auteurs principaux: Shiddique, Sheikh Noman, Nushin, Syeda Samiha, Mondal, Bipanko Kumar, Abir, Ahnaf Tahmid, Rahman, Md. Mahbubor, Hossain, Mainul, Hossain, Jaker
Format: Preprint
Publié: 2024
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author Shiddique, Sheikh Noman
Nushin, Syeda Samiha
Mondal, Bipanko Kumar
Abir, Ahnaf Tahmid
Rahman, Md. Mahbubor
Hossain, Mainul
Hossain, Jaker
author_facet Shiddique, Sheikh Noman
Nushin, Syeda Samiha
Mondal, Bipanko Kumar
Abir, Ahnaf Tahmid
Rahman, Md. Mahbubor
Hossain, Mainul
Hossain, Jaker
contents Zinc telluride (ZnTe) thin films have special semiconducting characteristics that make them very promising for a broad range of optoelectronic applications. In this work, a novel approach for synthesizing ZnTe thin films by spin coating technique is followed using a unique solution process with ZnTe directly dissolving in thiol-amine co-solvents. Thin films are synthesized on glass substrates and air annealed at 250-350 °C. The polycrystalline phase of ZnTe is revealed through the X-ray diffraction (XRD) study. The scanning electron microscopy (SEM) is used to observe the evolution of surface smoothness with annealing temperature. Moreover, elemental compositions of ZnTe thin film have been determined by energy dispersive spectroscopy (EDS) study. FTIR spectroscopy reveals that ZnTe has been successfully synthesized as confirmed by the characteristic peaks in the spectrum of 750-1000 cm-1. Optical properties of the ZnTe thin films have been investigated using UV-vis spectroscopy. The transmittance of the films increases with annealing temperature. Furthermore, the optical bandgaps of the films of 2.92, 2.84, and 2.5 eV have been found at 250, 300, and 350 °C annealing temperatures, respectively. These results suggest that controlling the annealing environment serves as a valuable strategy for tailoring the ZnTe film properties to meet specific application requirements. These results reveal that spin coated ZnTe thin films are attractive ones for various applications in optoelectronic devices such as solar cells and photodetectors.
format Preprint
id arxiv_https___arxiv_org_abs_2403_11554
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Thiol-amine co-solvents aided direct synthesis of ZnTe thin films by spin coating for low cost optoelectronic applications
Shiddique, Sheikh Noman
Nushin, Syeda Samiha
Mondal, Bipanko Kumar
Abir, Ahnaf Tahmid
Rahman, Md. Mahbubor
Hossain, Mainul
Hossain, Jaker
Materials Science
Zinc telluride (ZnTe) thin films have special semiconducting characteristics that make them very promising for a broad range of optoelectronic applications. In this work, a novel approach for synthesizing ZnTe thin films by spin coating technique is followed using a unique solution process with ZnTe directly dissolving in thiol-amine co-solvents. Thin films are synthesized on glass substrates and air annealed at 250-350 °C. The polycrystalline phase of ZnTe is revealed through the X-ray diffraction (XRD) study. The scanning electron microscopy (SEM) is used to observe the evolution of surface smoothness with annealing temperature. Moreover, elemental compositions of ZnTe thin film have been determined by energy dispersive spectroscopy (EDS) study. FTIR spectroscopy reveals that ZnTe has been successfully synthesized as confirmed by the characteristic peaks in the spectrum of 750-1000 cm-1. Optical properties of the ZnTe thin films have been investigated using UV-vis spectroscopy. The transmittance of the films increases with annealing temperature. Furthermore, the optical bandgaps of the films of 2.92, 2.84, and 2.5 eV have been found at 250, 300, and 350 °C annealing temperatures, respectively. These results suggest that controlling the annealing environment serves as a valuable strategy for tailoring the ZnTe film properties to meet specific application requirements. These results reveal that spin coated ZnTe thin films are attractive ones for various applications in optoelectronic devices such as solar cells and photodetectors.
title Thiol-amine co-solvents aided direct synthesis of ZnTe thin films by spin coating for low cost optoelectronic applications
topic Materials Science
url https://arxiv.org/abs/2403.11554