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| Main Authors: | , , |
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| Format: | Preprint |
| Published: |
2024
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2403.13782 |
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Table of Contents:
- Slurry electrodes are an effective means to improve flow battery performance by reducing electrode fouling and increasing the active surface area necessary for electrochemical reactions. It is critical to understand how the slurry formulation impacts its rheological profile and ultimately battery performance. We study the linear and nonlinear rheology of activated carbon (AC) based slurry electrode used in an all-iron flow battery in the presence of a nonionic surfactant (Triton X-100). Our results show the slurry mimics a colloidal gel with elasticity remaining constant despite increasing surfactant concentration until $α$(=C$_{surf.}$/C$_{AC}$) < 0.65. However, at $α\ge$ 0.65, the slurry abruptly transitions to a fluid with no measurable yield stress. This critical surfactant concentration at which the rheological profile undergoes a dynamic change matches the concentration found previously for gel collapse of this system. Moreover, this transition is accompanied by a complete loss of electrical conductivity. These data show that site specific adsorption of surfactant molecules often used in slurry formulation have a significant and dramatic impact on flow behavior, which should be considered when formulating a slurry electrode.