Determining the chemical composition of diamagnetic mixed solids via measurements of the magnetic susceptibility
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arXiv
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| Natura: | Preprint |
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2024
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| author | Zhao, Miao Miao Yang, Yang Du, Na Zhu, Yu Ying Ren, Peng Yen, Fei |
| author_facet | Zhao, Miao Miao Yang, Yang Du, Na Zhu, Yu Ying Ren, Peng Yen, Fei |
| contents | Mixed solid compounds are employed in a vast array of applications so an accurate determination of their chemical compositions is of crucial importance. All current characterization methods require specially-treated samples so the availability of a more practical method with similar accuracy should alleviate the quantification process. In this work, we show how the doping concentration $δ$ (or isotope concentration) of a mixed solid compound in powdered form, where both parent compounds are diamagnetic, can be obtained from the measurement of the mass magnetization. We exploit the additive nature of the molar magnetic susceptibility $χ_{Mol}$ and molar mass to construct two equations with the same two unknowns in the $χ_{Mol}$ vs. $δ$ space to simultaneously solve $χ_{Mol}$ and $δ$ of a mixed solid. Eight examples are provided to show the wide applicability of this method: NH$_{4(1-δ)}$D$_{4δ}$Br (where D = $^2$H), NH$_4$I$_{1-δ}$Br$_δ$, (NH$_4$H$_2$)$_{1-δ}$(ND$_4$D$_2$)$_δ$PO$_4$, C$_{48}$H$_{22+6δ}$Br$_{6(1-δ)}$O$_{32}$Zr$_6$, [creatine]$_{1-δ}$[$_D$-glucose]$_δ$, [$_L$-glutamic acid]$_{1-δ}$[$_L$-leucine]$_δ$, [terephthalic acid]$_{1-δ}$[trimesic acid]$_δ$ and [p-terphenyl]$_{1-δ}$[triphenylphosphine]$_δ$. Experimental errors of ~1.2% were obtained for $δ$ from average sample masses of 16.6 mg in powdered form rendering the presented approach an attractive choice for characterizing the ratios of mixed solids. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2404_02012 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Determining the chemical composition of diamagnetic mixed solids via measurements of the magnetic susceptibility Zhao, Miao Miao Yang, Yang Du, Na Zhu, Yu Ying Ren, Peng Yen, Fei Materials Science Chemical Physics Mixed solid compounds are employed in a vast array of applications so an accurate determination of their chemical compositions is of crucial importance. All current characterization methods require specially-treated samples so the availability of a more practical method with similar accuracy should alleviate the quantification process. In this work, we show how the doping concentration $δ$ (or isotope concentration) of a mixed solid compound in powdered form, where both parent compounds are diamagnetic, can be obtained from the measurement of the mass magnetization. We exploit the additive nature of the molar magnetic susceptibility $χ_{Mol}$ and molar mass to construct two equations with the same two unknowns in the $χ_{Mol}$ vs. $δ$ space to simultaneously solve $χ_{Mol}$ and $δ$ of a mixed solid. Eight examples are provided to show the wide applicability of this method: NH$_{4(1-δ)}$D$_{4δ}$Br (where D = $^2$H), NH$_4$I$_{1-δ}$Br$_δ$, (NH$_4$H$_2$)$_{1-δ}$(ND$_4$D$_2$)$_δ$PO$_4$, C$_{48}$H$_{22+6δ}$Br$_{6(1-δ)}$O$_{32}$Zr$_6$, [creatine]$_{1-δ}$[$_D$-glucose]$_δ$, [$_L$-glutamic acid]$_{1-δ}$[$_L$-leucine]$_δ$, [terephthalic acid]$_{1-δ}$[trimesic acid]$_δ$ and [p-terphenyl]$_{1-δ}$[triphenylphosphine]$_δ$. Experimental errors of ~1.2% were obtained for $δ$ from average sample masses of 16.6 mg in powdered form rendering the presented approach an attractive choice for characterizing the ratios of mixed solids. |
| title | Determining the chemical composition of diamagnetic mixed solids via measurements of the magnetic susceptibility |
| topic | Materials Science Chemical Physics |
| url | https://arxiv.org/abs/2404.02012 |