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Main Authors: Burau, Justin J., Mehling, Kameron, Frye, Matthew D., Chen, Mengjie, Aggarwal, Parul, Hutson, Jeremy M., Ye, Jun
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2404.06652
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author Burau, Justin J.
Mehling, Kameron
Frye, Matthew D.
Chen, Mengjie
Aggarwal, Parul
Hutson, Jeremy M.
Ye, Jun
author_facet Burau, Justin J.
Mehling, Kameron
Frye, Matthew D.
Chen, Mengjie
Aggarwal, Parul
Hutson, Jeremy M.
Ye, Jun
contents Efficient sub-Doppler laser cooling and optical trapping of YO molecules offer new opportunities to study collisional dynamics in the quantum regime. Confined in a crossed optical dipole trap, we achieve the highest phase-space density of $2.5 \times 10^{-5}$ for a bulk laser-cooled molecular sample. This sets the stage to study YO--YO collisions in the microkelvin temperature regime, and reveal state-dependent, single-partial-wave two-body collisional loss rates. We determine the partial-wave contributions to loss of specific rotational states (first excited $N=1$ and ground $N=0$) following two strategies. First, we measure the change of the collision rate in a spin mixture of $N=1$ by tuning the kinetic energy with respect to the p- and d-wave centrifugal barriers. Second, we compare loss rates between a spin mixture and a spin-polarized state in $N=0$. Using quantum defect theory with a partially absorbing boundary condition at short range, we show that the dependence on temperature for $N=1$ can be reproduced in the presence of a d-wave or f-wave resonance, and the dependence on a spin mixture for $N=0$ with a p-wave resonance.
format Preprint
id arxiv_https___arxiv_org_abs_2404_06652
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Collisions of Spin-polarized YO Molecules for Single Partial Waves
Burau, Justin J.
Mehling, Kameron
Frye, Matthew D.
Chen, Mengjie
Aggarwal, Parul
Hutson, Jeremy M.
Ye, Jun
Atomic Physics
Efficient sub-Doppler laser cooling and optical trapping of YO molecules offer new opportunities to study collisional dynamics in the quantum regime. Confined in a crossed optical dipole trap, we achieve the highest phase-space density of $2.5 \times 10^{-5}$ for a bulk laser-cooled molecular sample. This sets the stage to study YO--YO collisions in the microkelvin temperature regime, and reveal state-dependent, single-partial-wave two-body collisional loss rates. We determine the partial-wave contributions to loss of specific rotational states (first excited $N=1$ and ground $N=0$) following two strategies. First, we measure the change of the collision rate in a spin mixture of $N=1$ by tuning the kinetic energy with respect to the p- and d-wave centrifugal barriers. Second, we compare loss rates between a spin mixture and a spin-polarized state in $N=0$. Using quantum defect theory with a partially absorbing boundary condition at short range, we show that the dependence on temperature for $N=1$ can be reproduced in the presence of a d-wave or f-wave resonance, and the dependence on a spin mixture for $N=0$ with a p-wave resonance.
title Collisions of Spin-polarized YO Molecules for Single Partial Waves
topic Atomic Physics
url https://arxiv.org/abs/2404.06652