Solvent-antisolvent interactions in metal halide perovskites

Fuente: arXiv
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Autori principali: Bautista-Quijano, Jose Roberto, Telschow, Oscar, Paulus, Fabian, Vaynzof, Yana
Natura: Preprint
Pubblicazione: 2024
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author Bautista-Quijano, Jose Roberto
Telschow, Oscar
Paulus, Fabian
Vaynzof, Yana
author_facet Bautista-Quijano, Jose Roberto
Telschow, Oscar
Paulus, Fabian
Vaynzof, Yana
contents The fabrication of metal halide perovskite films using the solvent-engineering method is increasingly common. In this method, the crystallisation of the perovskite layer is triggered by the application of an antisolvent during the spin-coating of a perovskite precursor solution. Herein, we introduce the current state of understanding of the processes involved in the crystallisation of perovskite layers formed by solvent engineering, focusing in particular on the role of antisolvent properties and solvent-antisolvent interactions. By considering the impact of the Hansen solubility parameters, we propose guidelines for selecting the appropriate antisolvent and outline open questions and future research directions for the fabrication of perovskite films by this method.
format Preprint
id arxiv_https___arxiv_org_abs_2404_11637
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Solvent-antisolvent interactions in metal halide perovskites
Bautista-Quijano, Jose Roberto
Telschow, Oscar
Paulus, Fabian
Vaynzof, Yana
Materials Science
The fabrication of metal halide perovskite films using the solvent-engineering method is increasingly common. In this method, the crystallisation of the perovskite layer is triggered by the application of an antisolvent during the spin-coating of a perovskite precursor solution. Herein, we introduce the current state of understanding of the processes involved in the crystallisation of perovskite layers formed by solvent engineering, focusing in particular on the role of antisolvent properties and solvent-antisolvent interactions. By considering the impact of the Hansen solubility parameters, we propose guidelines for selecting the appropriate antisolvent and outline open questions and future research directions for the fabrication of perovskite films by this method.
title Solvent-antisolvent interactions in metal halide perovskites
topic Materials Science
url https://arxiv.org/abs/2404.11637