Effects of Reduced Interlayer Interactions on the K-point Excitons of MoS$_2$ Nanoscrolls
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arXiv
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| Autores principales: | , , , , , , , , |
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| Formato: | Preprint |
| Publicado: |
2024
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| _version_ | 1866911056407822336 |
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| author | Chatterjee, Sagnik Chowdhury, Tamaghna Núñez, Pablo Díaz Kay, Nicholas Rajput, Manisha Hwang, Sooyeon Timokhin, Ivan Mishchenko, Artem Rahman, Atikur |
| author_facet | Chatterjee, Sagnik Chowdhury, Tamaghna Núñez, Pablo Díaz Kay, Nicholas Rajput, Manisha Hwang, Sooyeon Timokhin, Ivan Mishchenko, Artem Rahman, Atikur |
| contents | Transition metal dichalcogenide (TMD) nanoscrolls (NS) exhibit significant photoluminescence (PL) signals despite their multilayer structure, which cannot be explained by the strained multilayer description of NS. Here, we investigate the interlayer interactions in NS to address this discrepancy. The reduction of interlayer interactions in NS is attributed to two factors: (1) the symmetry-broken mixed stacking order between neighbouring layers due to misalignment, and (2) the high inhomogeneity in the strain landscape resulting from the unique Archimedean spiral-like geometry with positive eccentricity. These were confirmed through transmission electron microscopy, field emission scanning electron microscopy and atomic force microscopy. To probe the effect of reduction of interlayer interactions in multilayered MoS$_2$ nanoscrolls, low-temperature PL spectroscopy was employed investigating the behaviour of K-point excitons. The effects of reduced interlayer interactions on exciton-phonon coupling (EXPC), exciton energy, and exciton oscillator strength are discussed, providing insights into the unique properties of TMD nanoscrolls. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2404_12250 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Effects of Reduced Interlayer Interactions on the K-point Excitons of MoS$_2$ Nanoscrolls Chatterjee, Sagnik Chowdhury, Tamaghna Núñez, Pablo Díaz Kay, Nicholas Rajput, Manisha Hwang, Sooyeon Timokhin, Ivan Mishchenko, Artem Rahman, Atikur Mesoscale and Nanoscale Physics Materials Science Transition metal dichalcogenide (TMD) nanoscrolls (NS) exhibit significant photoluminescence (PL) signals despite their multilayer structure, which cannot be explained by the strained multilayer description of NS. Here, we investigate the interlayer interactions in NS to address this discrepancy. The reduction of interlayer interactions in NS is attributed to two factors: (1) the symmetry-broken mixed stacking order between neighbouring layers due to misalignment, and (2) the high inhomogeneity in the strain landscape resulting from the unique Archimedean spiral-like geometry with positive eccentricity. These were confirmed through transmission electron microscopy, field emission scanning electron microscopy and atomic force microscopy. To probe the effect of reduction of interlayer interactions in multilayered MoS$_2$ nanoscrolls, low-temperature PL spectroscopy was employed investigating the behaviour of K-point excitons. The effects of reduced interlayer interactions on exciton-phonon coupling (EXPC), exciton energy, and exciton oscillator strength are discussed, providing insights into the unique properties of TMD nanoscrolls. |
| title | Effects of Reduced Interlayer Interactions on the K-point Excitons of MoS$_2$ Nanoscrolls |
| topic | Mesoscale and Nanoscale Physics Materials Science |
| url | https://arxiv.org/abs/2404.12250 |